The preparation and catalytic hydroformylation activity of some halocarbonylrhodium(I) complexes containing phosphinoalkylorganosilicon ligands

Farrell, M. O.; Dyke, C. H. Van; Boucher, L. J.; Metlin, Sol

doi:10.1016/s0022-328x(00)81159-6

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Cited by 16 publications

(1 citation statement)

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“…Several silylmonophosphine ligands have also been used in catalysis. Farrell et al have examined several rhodium complexes of silylmonophosphines as catalysts in the hydroformylation of hex-1-ene [102]. The results are summarized in Table 7.…”

Section: ð16þmentioning

confidence: 99%

Silicon based phosphines with P_Si_P, P_C_Si_C_P and P_O_Si_O_P linkages and their coordination chemistry and catalytic applications

Balakrishna

Chandrasekaran

George

2003

Coordination Chemistry Reviews

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Section: ð16þmentioning

confidence: 99%

Silicon based phosphines with P_Si_P, P_C_Si_C_P and P_O_Si_O_P linkages and their coordination chemistry and catalytic applications

Balakrishna

Chandrasekaran

George

2003

Coordination Chemistry Reviews

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Silsesquioxanes as models of silica supported catalyst I. [3-(Diphenylphosphino)propyl]-hepta[propyl]-[octasilsesquioxane] and [3-mercapto-propyl]-hepta[propyl]-[octasilsesquioxane] as ligands for transition-metal ions

Hendan

Marsmann

1999

Appl. Organometal. Chem.

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The ligand [3‐(diphenylphosphino)propyl]‐hepta[propyl]‐[octasilsesquioxane] (dpps) can be prepared by reacting [3‐chloropropyl]‐hepta[propyl]‐[octasilsesquioxane] (cs) with KP(Ph)2. The transition‐metal complexes [Rh(CO)(dpps)2Cl], [Rh(COD)(dpps)Cl] and [Pt(dpps)2Cl2] are synthesized as models of functionalized silica‐gel surfaces. Without destruction of the siloxane cage, the intermediate compounds Hg(ss)2, and Pb(ss)2 are obtained from [3‐mercaptopropyl]‐hepta[propyl]‐[octasilsesquioxane] (ssH). Starting from Pb(ss)2, the transition‐metal complexes [Au(ss)(P(Ph)3)], [Rh(ss)(CO)2]2 and [Rh(ss)(COD)]2 are accessible. The compounds have been characterized mostly by 1H, 13C, 29Si and 31P NMR spectroscopy. Copyright © 1999 John Wiley & Sons, Ltd.

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ChemInform Abstract: THE PREPARATION AND CATALYTIC HYDROFORMYLATION ACTIVITY OF SOME HALOCARBONYLRHODIUM(I) COMPLEXES CONTAINING PHOSPHINOALKYLORGANOSILICON LIGANDS

Farrell¹,

Dyke²,

Boucher³

et al. 1979

Chemischer Informationsdienst

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The preparation and catalytic hydroformylation activity of some halocarbonylrhodium(I) complexes containing phosphinoalkylorganosilicon ligands

Cited by 16 publications

References 21 publications

Silicon based phosphines with P_Si_P, P_C_Si_C_P and P_O_Si_O_P linkages and their coordination chemistry and catalytic applications

Silicon based phosphines with P_Si_P, P_C_Si_C_P and P_O_Si_O_P linkages and their coordination chemistry and catalytic applications

Silsesquioxanes as models of silica supported catalyst I. [3-(Diphenylphosphino)propyl]-hepta[propyl]-[octasilsesquioxane] and [3-mercapto-propyl]-hepta[propyl]-[octasilsesquioxane] as ligands for transition-metal ions

ChemInform Abstract: THE PREPARATION AND CATALYTIC HYDROFORMYLATION ACTIVITY OF SOME HALOCARBONYLRHODIUM(I) COMPLEXES CONTAINING PHOSPHINOALKYLORGANOSILICON LIGANDS

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