The Preparation of 1,2-Dimethylarsinohexafluorocyclopentene, 1,2-Dimethylarsinooctafluorocyclohexene, and Related Mixed Ligands

Abstract

Dimethylarsine reacts with the compounds [Formula: see text] to give the ligands[Formula: see text]fnfars(n = 4, 6, 8) The reaction of diphenylphosphine with [Formula: see text] results in the mixed ligands[Formula: see text]fnAsP (n = 4, 6, 8)

Monosubstituted Derivatives of (L–L)Fe2(CO)6 (L–L = fluorocarbon bridged ligand)

“…The fluorocarbon-bridged ligands f.AsP (n = 4, 6), and f,,fos and f.fars (n = 4, 6, 8) were prepared using published procedures (2,5).…”

Ditertiary(phosphines and arsines) with perfluoro-(bi-1-cycloalken-1-yl) bridging groups. Preparation and properties including a solid state structure of a tetracarbonylmolybdenum derivative

“…Benzene was distilled over LiA1H4 prior to use. 2,2'-Dichlorooctafluoro-(bi-1-cyclobuten-1-yl) was prepared as indicated in [2] (4) as was the dodecafluoro(bi-1-cyclopenten-1-yl) analogue.…”

“…1, when n = 2 and X = F, only For personal use only. disubstitution has ever been obtained with diphenylphosphine (1, 1 1) (the product is known as f4fos) yet dimethylarsine gives monosubstitution at 25 OC and disubstitution at 150 OC (2,11).…”