The purpose of the study was to assess the state and degree of exhaustion of turbine rotor materials made of low-alloy Cr-Mo-V steels after long-term operation. The tests were carried out for selected structure states defined on the basis of images of the structure observed using a scanning electron microscope, and the degree of development of precipitation processes based on the X-ray analysis of the phase composition of electrolytically isolated carbide deposits. For materials with such defined structure states and degree of development of precipitation processes, the following were determined: mechanical properties at room and elevated temperatures, residual life and available residual life on the basis of short-term creep tests, and creep rate from creep curves for temperature and stress parameters corresponding to operational parameters. Based on the results of short-term creep tests conducted at a temperature higher than the operational temperature and with a stress corresponding to the operational life, residual and available residual life were determined and the degree of exhaustion was estimated.