Fission yield measurements have been carried out in the mass region 99–106 in order to investigate the postulated complementary fission‐yield fine structure. Data were obtained in the mass region for U235 (n, f), U238 (γ, f), U235 (d, f) and U238 (d, f). Fine structure was found in all cases. It was found that the mass position of this fine structure can be explained adequately using the assumption that primary fission fragments with 82 neutrons or 50 protons, and the complements of these fragments, have an enhanced yield. This enhancement of yield is felt to be a result of selectivity in the fission process itself, as opposed to other fine structure effects, known to arise after the fission process. The mass position of complementary fine structure is predicted for several cases which have not yet been investigated. No attempt is made to explain the absolute amount of yield enhancement.