The pseudo-catalytic promotion of nitric oxide oxidation by ethane at low temperatures

The effect of a DC electric field on the laminar burning velocity of premixed methane/air flames

“…3.0 with initial concentrations of radicals CH 3 , CH 2 , CH, and C as input parameters. A similar approach was used by Naidis [38] to model ignition due to transient plasma discharges, implementing the updated Konnov mechanism [39] and varying initial concentrations of atoms generated by discharge.…”

Sensitizing effects of NOx on CH4 oxidation at high pressure

“…This interaction has been investigated for a wide range of fuels, including H 2 [3,4], CO [4][5][6][7], CH 2 O [3,8], CH 4 /natural gas [3,4,[9][10][11][12][13][14][15][16][17][18][19][20][21], C 2 hydrocarbons [4,12,[22][23][24], higher hydrocarbons [4,12,[25][26][27][28], and oxygenated hydrocarbons [29][30][31][32][33][34][35]. The sensitizing behavior is a result of interactions with the radical pool as well as direct reactions between NO x and stable species, e.g., H 2 , O 2 , CH 2 O, CH 4 , and C 2 H 6 .…”

Combustion and Pyrolysis Kinetics of Chloropicrin

“…Recently, a new mechanism for HCl combustion has been proposed by Pelucchi et al 29 A mechanism specific to chloropicrin has been developed in this work, in which were included unimolecular initiations, chlorine-atom abstractions, decomposition of the radicals formed, chlorine-nitrogen coupling reactions, as well as some oxidation reactions not included in kinetic models of chlorinated and nitrogenous species. The thermochemical properties were taken from the literature in the case of light species involved in the nitrogen and chlorine sub-mechanisms [27][28][29] , and theoretically calculated for chloropicrin and related products. Main species theoretically studied are presented in Table 1.…”