The Purification and Physical Constants of Aromatic Hydrocarbons

Gibbons, L. C.; Thompson, Jamie F.; Reynolds, T. W.; Wright, J. I.; Chanan, Henry H.; Lamberti, J. M.; Hipsher, Harold F.; Karabinos, J. V.

doi:10.1021/ja01210a503

Cited by 18 publications

(2 citation statements)

References 2 publications

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“…In fact, only one substantive reference was found to thermophysical property measurements on a sample of high purity. Gibbons et al (1945) reported a (Daubert and Danner, 1993). Key: (0) Wegscheider et al (1911); (O) Kraus et al (1962); (b) Kucharenko and Grigor'eva (1970);(3) DuPont (1970); (×) Bodnaryuk et al (1972); (4) Murogova et al (1974).…”

Section: Discussionmentioning

confidence: 99%

Vapor Pressure, Heat Capacity, and Density along the Saturation Line, Measurements for Dimethyl Isophthalate, Dimethyl Carbonate, 1,3,5-Triethylbenzene, Pentafluorophenol, 4-tert-Butylcatechol, α-Methylstyrene, andN,N‘-Bis(2-hydroxyethyl)ethylenediamine

et al. 1997

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This paper reports measurements made for DIPPR Research Project 821 in the 1993 Project Year. Vapor pressures were measured to a pressure limit of 270 kPa or lower decomposition point for all seven compounds using a twin ebulliometric system and, for dimethyl isophthalate and N,N′-bis(2-hydroxyethyl)ethylenediamine, additionally an inclined-piston apparatus. Liquid-phase densities along the saturation line were measured for each compound over a range of temperature (ambient to a maximum of 548 K). A differential scanning calorimeter (DSC) was used to measure two-phase (liquid + vapor) heat capacities for each compound in the temperature region ambient to the critical temperature or lower decomposition point. Where possible, the critical temperature and critical density for each compound were determined experimentally. The results of the measurements were combined to derive a series of thermophysical properties including critical temperature, critical density, critical pressure, acentric factor, enthalpies of vaporization (restricted to within (50 K of the temperature region of the experimentally determined vapor pressures), enthalpies of fusion if solid at ambient temperature, solubility parameter, and heat capacities along the saturation line. Wagner-type vapor-pressure equations were derived for each compound. In addition, the liquid-phase densities were compared with values derived using a threeterm [(1 -T r ) 1/3 ] power series. All measured and derived values were compared with those obtained in a search of the literature. Recommended critical parameters are listed for each of the compounds studied. A "Rule-Of-Thumb" derived in the 1992 Project Year is used to estimate thermal decomposition temperatures by radical scission from a knowledge of the bond dissociation energy or vice versa.

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Section: Discussionmentioning

confidence: 99%

Vapor Pressure, Heat Capacity, and Density along the Saturation Line, Measurements for Dimethyl Isophthalate, Dimethyl Carbonate, 1,3,5-Triethylbenzene, Pentafluorophenol, 4-tert-Butylcatechol, α-Methylstyrene, andN,N‘-Bis(2-hydroxyethyl)ethylenediamine

et al. 1997

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“…Boiling points measured in experiments at 101.3 kPa for toluene, o -chlorotoluene, and p -chlorotoluene were compared with data from published papers − as shown in Table .…”

Section: Methodsmentioning

confidence: 99%

Measurement and Correlation of Vapor–Liquid Equilibrium Data of the Toluene, o-Chlorotoluene, and p-Chlorotoluene System at 101.3 kPa

Wang

et al. 2022

J. Chem. Eng. Data

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Toluene, an excellent organic solvent, is used in various chemical reactants and carbon nanomaterials, and its recycling can potentially alleviate related environmental problems. Isobaric vapor− liquid equilibrium (VLE) data at 101.3 kPa for (toluene + ochlorotoluene), (toluene + p-chlorotoluene), and (o-chlorotoluene + pchlorotoluene) were measured in this study. The experimental data were tested using the Fredenslund test and the Van Ness test. NRTL, Wilson, and UNIQUAC models were employed to correlate the new VLE data, depicting that all models were fitted well. The above three activity coefficient models were used to regress the binary interaction parameters, where the root-mean-square deviation (RMSD) and the average absolute deviation (AAD) results indicated that the experimental and thermodynamic model data were within a reasonable range. Although VLE data showed that the binary systems are non-azeotropic, toluene and o-chlorotoluene, or toluene and p-chlorotoluene are well separated by rectification, and the separation of o-chlorotoluene and p-chlorotoluene using distillation may need a significant number of stages.

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Recherches sur la Température de Congélation des substances organiques XVI.‐Nouvelles Déterminations expérimentales

Timmermans

1952

Bulletin des Soc Chimique

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The Purification and Physical Constants of Aromatic Hydrocarbons

Cited by 18 publications

References 2 publications

Vapor Pressure, Heat Capacity, and Density along the Saturation Line, Measurements for Dimethyl Isophthalate, Dimethyl Carbonate, 1,3,5-Triethylbenzene, Pentafluorophenol, 4-tert-Butylcatechol, α-Methylstyrene, andN,N‘-Bis(2-hydroxyethyl)ethylenediamine

Vapor Pressure, Heat Capacity, and Density along the Saturation Line, Measurements for Dimethyl Isophthalate, Dimethyl Carbonate, 1,3,5-Triethylbenzene, Pentafluorophenol, 4-tert-Butylcatechol, α-Methylstyrene, andN,N‘-Bis(2-hydroxyethyl)ethylenediamine

Measurement and Correlation of Vapor–Liquid Equilibrium Data of the Toluene, o-Chlorotoluene, and p-Chlorotoluene System at 101.3 kPa

Recherches sur la Température de Congélation des substances organiques XVI.‐Nouvelles Déterminations expérimentales

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