2020
DOI: 10.26434/chemrxiv.11911077.v2
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The Pyruvate Aldol Condensation Product: A Metabolite that Escaped Synthetic Preparation for Over a Century

Abstract: <p>The homo-aldol condensation product of pyruvate, <a>2-methyl-4-oxopent-2-enedioic acid (OMPD) </a>has been recently implicated as a catabolic intermediate in the bacterial degradation of lignin and previously identified from other biological sources in reports ranging over sixty years. Yet, while a preparation of the pyruvate aldol-product precursor, 4-hydroxy-4-methyl-2-oxoglutaric acid (HMOG) was first reported in 1901, there has not been a complete published synthesis of OMPD. Analysis… Show more

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