The ancient Benin moat of 2.00 to 5.00 m width, and 10 to 30 m depth almost concentrically dug round the City, is supposed to be an important socio-cultural artifact if well preserved. It has served its good purpose of defense and protection of the ancient Bini civilization. Now, modern urbanization pressure has defaced and is degrading the moat and its environs through house development, soil quarrying, gullying, flood catchment, and waste disposal. Because of its extent, it is pertinent to understand its pedo-geological and hydrogeological setting in order to assess the impact of the waste disposal on the soil and groundwater systems. Random; 11 soil (pool) samples at 0.0 to 0.5 m depth, and eight groundwater samples from pumping boreholes, 0.5 to 10.0 m on both sides of the moat were drawn. Samples were analyzed for their chemical, heavy metal constituents (including microbial in water). Comparisons of means with pristine locations in previous studies were conducted using one way analysis of variance (ANOVA) at 5% α level of significance. Results reveal contamination of soil with Al, Cd, Fe, Pb and THC at P<0.05. The groundwater also is polluted with presumptive coliform of 1.0 x 10 2 to 1.5 x 10 3 cfu/ml -1 and heavy metals; Al, Cd, and Pb at P<0.01 indicating high significant difference. This indicates that the once protective moat is now a likely area of phytotoxicity and general environmental toxicity to man if chronic exposure is allowed by continual waste disposal.