This paper presents the detailed abundances and r-process classifications of 126 newly identified metal-poor stars as part of an ongoing collaboration, the R-Process Alliance. The stars were identified sakaricm@u.washington.edu 2 Sakari et al.as metal-poor candidates from the RAdial Velocity Experiment (RAVE) and were followed-up at high spectral resolution (R ∼ 31, 500) with the 3.5 m telescope at Apache Point Observatory. The atmospheric parameters were determined spectroscopically from Fe I lines, taking into account <3D> non-LTE corrections and using differential abundances with respect to a set of standards. Of the 126 new stars, 124 have [Fe/H] < −1.5, 105 have [Fe/H] < −2.0, and 4 have [Fe/H] < −3.0. Nine new carbonenhanced metal-poor stars have been discovered, 3 of which are enhanced in r-process elements. Abundances of neutron-capture elements reveal 60 new r-I stars (with +0.3 ≤ [Eu/Fe] ≤ + 1.0 and [Ba/Eu] < 0) and 4 new r-II stars (with [Eu/Fe] > +1.0). Nineteen stars are found to exhibit a "limited-r" signature ([Sr/Ba] > +0.5, [Ba/Eu] < 0). For the r-II stars, the second-and third-peak main r-process patterns are consistent with the r-process signature in other metal-poor stars and the Sun. The abundances of the light, α, and Fe-peak elements match those of typical Milky Way halo stars, except for one r-I star which has high Na and low Mg, characteristic of globular cluster stars. Parallaxes and proper motions from the second Gaia data release yield UV W space velocities for these stars which are consistent with membership in the Milky Way halo. Intriguingly, all r-II and the majority of r-I stars have retrograde orbits, which may indicate an accretion origin.