1967
DOI: 10.1016/0038-1098(67)90791-0
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The Raman spectrum of BaTiO3

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Cited by 110 publications
(34 citation statements)
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“…11 The phonon wavenumbers are also expected to shift towards higher/lower values depending upon the tensile/compressive nature of the stress. 12 The Raman wavenumbers observe for the ceramics in this study were P. S. Dobal et al found to be comparable to those of single crystals, 13,14 which suggests the stress-free nature and larger grain size of the ceramics. However, different wavenumbers have been observed in films due to stresses caused by the differences in lattice parameters and thermal expansion coefficients of the film and substrate material.…”
Section: Solid Solutions Of Batio 3 Such As Bazr X Ti 1 X O 3 (Bzt)supporting
confidence: 59%
See 1 more Smart Citation
“…11 The phonon wavenumbers are also expected to shift towards higher/lower values depending upon the tensile/compressive nature of the stress. 12 The Raman wavenumbers observe for the ceramics in this study were P. S. Dobal et al found to be comparable to those of single crystals, 13,14 which suggests the stress-free nature and larger grain size of the ceramics. However, different wavenumbers have been observed in films due to stresses caused by the differences in lattice parameters and thermal expansion coefficients of the film and substrate material.…”
Section: Solid Solutions Of Batio 3 Such As Bazr X Ti 1 X O 3 (Bzt)supporting
confidence: 59%
“…All the Raman modes observed in the tetragonal phase have already been reported and discussed in the literature. 10,13,14 The tetragonal to cubic transition occurred about 137,97,27 and 7°C for x D 0.00, 0.10, 0.30 and 0.35 respectively. Two very broad bands centered at about 288 and 516 cm 1 characterized the cubic paraelectric phase.…”
Section: Solid Solutions Of Batio 3 Such As Bazr X Ti 1 X O 3 (Bzt)mentioning
confidence: 99%
“…It consisted Raman bands from two phases, tetragonal and orthorhombic phase, denoting with solid arrows and dash arrow respectively. Comparing to Raman spectrum of the single crystal BaTiO 3 [8][9][10], we assigned the spectrum as follows, a weak peak at 187. and 308.6 cm −1 [E (TO)], were the common character of tetragonal and orthorhombic symmetry. The phonon assignment was given inside square brackets.…”
Section: Resultsmentioning
confidence: 99%
“…Information about the shape of the unit cells of BTO1 and BTO2 were gained through Raman active vibration modes. 44 It was found that for a tetragonal unit cell a ferroelectric crystal is observed, while a cubit unit cell obviously did not exhibit ferroelectricity.…”
Section: Characterisation Of the Particlesmentioning
confidence: 99%