The Reaction of Haloamines with Ketenes

Coleman, George H.; Peterson, Rolf L.; Goheen, Gilbert E.

doi:10.1021/ja01301a015

Cited by 16 publications

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“…For example, from monoethanolamine and aniline, respectively, A'-hydroxyethylacetamide and acetanilide are formed. V-chloroacetamide, CH3CONCIH, results from the addition of chloramine, NH2C1, to ketene (21).…”

Section: Dehydroacetic Acidmentioning

confidence: 99%

Diketene A New Industrial Chemical

Boese¹

1940

Ind. Eng. Chem.

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Section: Dehydroacetic Acidmentioning

confidence: 99%

Diketene A New Industrial Chemical

Boese¹

1940

Ind. Eng. Chem.

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“…Divalent nitrogen species have been proposed as reactive intermediates in the free radical addition reactions of these positive halogen compounds with olefins (1)(2)(3)(4)(5)(6)(7)(8)(9)(10)(11)(12)(13)(14) as well as in their halogenation reactions involvillg hydrogen abstraction.…”

Section: Introductionmentioning

confidence: 99%

Metal ion initiated halogenation reactions of N-haloamines

Tanner¹,

Mosher²

1969

Can. J. Chem.

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The metal ion catalyzed chlorination of hydrocarbon substrates by N-chloroamines and imides in acid media proceeds by a free radical chain mechanism. Reactions of four different N-chloro halogenating reagents with cuprous chloride, ferrous sulfate, and ferrous chloride initiators have been investigated. Contrary to the previously reported observations no experimental differences were observed in the halogenation reactions of individual N-halo compounds or with the different initiators. The chain carrying species in all cases was shown to be the chlorine atom and the radical chain process showed identical reactivity to that of photo-chlorination by molecular chlorine.

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“…The addition of chloroamine and nitrogen trichloride to a wide variety of unsaturated organic compounds results in the formation of the corresponding amines and N-dichloroamines [7,8,9,11,12,13,14] .…”

Section: N-chloroamines Anddquo;mentioning

confidence: 99%

Active Chlorine Compounds—Their Chemistry and Application

Chenicek¹

1946

Textile Research Journal

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Active chlorine compounds form a group of substances capable of many useful reactions. In addition to their well-known bleaching properties, newer compounds of this class are finding unusual and specialized applicatians in the textile industry. It would appear that if the nature of these compounds were better known they would find wider usage in the industry. This article describes the chemistry of some of the known active chlorine compounds.

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The Reaction of Haloamines with Ketenes

Cited by 16 publications

References 0 publications

Diketene A New Industrial Chemical

Diketene A New Industrial Chemical

Metal ion initiated halogenation reactions of N-haloamines

Active Chlorine Compounds—Their Chemistry and Application

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