1970
DOI: 10.1016/s0031-9422(00)85281-4
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The reaction of thioglycolic acid with polyflavanoid bark fractions of Tsuga heterophylla

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Cited by 21 publications
(5 citation statements)
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“…Therefore, it is possible that the catechin moieties in these outer-bark polymers may have resulted from epimerization during the many years of storage in the outer bark. However, much higher proportions of catechin units are indicated in polymers from Douglas-fir bark (Karchesy et al, 1976) and western hemlock bark (Sears and Casebier, 1970), which have epicatechin to catechin ratios of 3:1 and 1:1. The optical rotations of the thioglycolates obtained from these polymers were not reported.…”
Section: I'v/ 'mentioning
confidence: 99%
“…Therefore, it is possible that the catechin moieties in these outer-bark polymers may have resulted from epimerization during the many years of storage in the outer bark. However, much higher proportions of catechin units are indicated in polymers from Douglas-fir bark (Karchesy et al, 1976) and western hemlock bark (Sears and Casebier, 1970), which have epicatechin to catechin ratios of 3:1 and 1:1. The optical rotations of the thioglycolates obtained from these polymers were not reported.…”
Section: I'v/ 'mentioning
confidence: 99%
“…132 This reaction was discussed by Sears and Casebier. 198 In scheme 1, we illustrate the application of this reaction to myricetin-3-rhamnoside. 102 Carob extracts are being studied in recent years for gastroprotective activities, and they were found highly active, so far.…”
Section: Discussionmentioning
confidence: 99%
“…While inoculation with B. mucronatus also resulted in production of phenols by the host, the response was much less dramatic. Tannins in bark of conifers are mainly condensed ones (Okamura, 1961;Sogo and Hata, 1967) and are polymers of flavanols such as catechin (Karchesy et al, 1976;Sears and Casebier, 1970). In the HPLC-chromatograms, the retention time of catechin coincides with that of the peak-1, the highest peak found in the chromatograms for pine metabolites.…”
Section: Discussionmentioning
confidence: 99%