The modulation of the surface of silicon stimulates its applications in optics (antireflection surface, solar cells, and photoelectric devices). In this work, an appropriate ratio of the O 2 to SF 6 plasma through reactive ion etching generated a double-layer Silicon nanograss (upper layer�flocculent SiO x F y passivation; lower layer� pointy silicon spike) on the surface of the silicon wafer. The height and density of Silicon nanograss can be controlled through process parameters (pressure, O 2 /SF 6 ratio, and RF power), mask spacing, and a variety of assistant substrates. The underlying formation mechanisms of Silicon nanograss disclosed that the sputtering of Al substrate acts as a micromask, i.e., primarily responsible for the formation of Silicon nanograss. Considering an in-depth study, a simple, low-cost, and CMOS-compatible method for wafer-level preparation of Silicon nanograss is provided. Specifically, the Silicon nanograss exhibited excellent antireflection and enhanced absorption properties. This work contributes to micro-nano surface science accompanied by optical applications.