The relative reactivities of azidoformates and sulfonyl azides with certain hydrocarbons

Short PET and PA fibre composites based on LDPE and HDPE matrices. Morphology-behaviour relationship

“…In the case of the polymer matrices used in the present study, which have not got any reactive group in their structure, it is not easy to find a suitable coupling agent. However, the unique chemical behaviour of the azide group permit its chemical link to any C1H bond 5,6) . Based on our previous experience, unmodified and azide-modified PET and PA short fibres composites based on LDPE and HDPE thermoplastic matrices have been prepared to compare their effect on the behaviour and morphology of these composites.…”

Photolysis of 2,4,6-Tri-t-butylnitrobenzene

“…The latter species are well known to intramolecularily insert readily into carbonhydrogen bonds which are sp2 hybridized (7). Nitrenes are least reactive towards primary carbon-hydrogen bonds which are sp3 hybridized (8). Alternatively, it is possible that 7 may rearrange directly to 2 (5).…”

Study on the reactions of pyridine with fluorine-containing compounds in the gas-phase by electron impact/Fourier transfer ion cyclotron resonance mass spectrometry

“…phenyl azide, alkane-or arene-sulfonyl azide and azidoformates, etc. ), on heating or irradiating give a nitrene intermediate R-N (R = aryl, R 0 OCO, R 0 SO 2 , ArSO 2 R f SO 2 ) [1][2][3][4][5]. The reaction of pyridines with sulfonyl azides was first studied by Curtius seventy years ago and the reaction product was incorrectly formulated as 2-, 3-or 4-aminopyridine derivatives RSO 2 NHAr [6].…”