We present optical spectroscopy of 62 objects selected from several samples of ultraÈsteep-spectrum radio sources. Forty-six of these are from our primary catalog, consisting of 669 sources with radio spectral indices a \ [1.30 this Ðrst spectroscopic subsample was selected on the basis of their faint (S l P la) ; optical and near-IR identiÐcations. Most are identiÐed as narrow-lined radio galaxies with redshifts ranging from z \ 0.25 to z \ 5.19. Ten objects are at z [ 3, nearly doubling the number of such sources known to date. Four of the USS radio sources are identiÐed with quasars, of which at least three have very red spectral energy distributions. The source TN J0936[2242 is identiÐed with an extremely red object (ERO, R[K [ 5) ; both it and a close companion are at z \ 1.479. The spectrum of the ERO closely resembles that of previously discovered radio galaxies at z D 1.5. Five sources show continuum emission, but fail to show any clear emission or absorption features, despite integrations of D1 hr with the Keck telescope. We suggest that these objects could be (1) radio galaxies with faint emission lines in the "" redshift desert ÏÏ at (2) radio galaxies with an obscured active galactic nucleus, which 1.5 [ z [ 2.3, are dominated by a stellar continuum observed with an insufficient signal-to-noise ratio, or (3) pulsars. Three radio sources identiÐed with faint objects in the K-band images remain undetected in 50È90 minute spectroscopic integrations with the Keck telescope, and are possible z [ 7 candidates.