“…Helianthemum and Dryas had lower pH values in the rhizosphere than in the bulk, so confirming the acidifying action that the roots exert on the soil in contact with them (e.g., Hinsinger et al, 2003). The acidification of the rhizosphere can occur by different processes, other than the CO 2 produced by the root respiration (Richter et al, 2007): 1) excretion of H þ following the root absorption of cations in excess of anions (Haynes, 1990), and 2) release of organic acids to overcome nutrient deficiency (Rengel and Romheld, 2000;Hinsinger et al, 2003;Sandnes et al, 2005). For example, in P deficient soils, roots of natural and cultivated plants exude large amounts of low-molecular weight carboxylates that mobilize P by competing for the same adsorption sites in the soil matrix (Gerke et al, 2000;Fern andez Sanjurjo et al, 2003;Wouterlood et al, 2005).…”