This manuscript has been reproduced from the microfilm master. UMI fihns the text directly from the original or copy submitted. Thus, some thesis and dissertation copies are in typewriter face, while others may be fi-om any type of computer printer.The quality of this reproduction is dependent upon the quality of the copy submitted. Broken or indistinct print, colored or poor quality illustrations and photographs, print bleedthrough, substandard margins, and improper alignment can adversely affect reproduction.In the unlikely event that the author did not send UMI a complete manuscript and there are missing pages, these will be noted. Also, if unauthorized copyright material had to be removed, a note will indicate the deletion.Oversize materials (e.g., maps, drawings, charts) are reproduced by sectioning the original, beginning at the upper left-hand corner and continuing from left to right in equal sections with small overlaps. Each original is also photographed in one exposure and is included in reduced form at the back of the book.Photographs included in the original manuscript have been reproduced xerographically in this copy. Higher quality 6" x 9" black and white photographic prints are available for any photographs or illustrations appearing in this copy for an additional charge. Contact UMI directly to order. Table 2. Proton-reducing reactions by the acetogenic bacteria [14,27,143,168]. 23 Table 3. The methanogenic bacteria [12], 26 Table 4. Methanogenic substrates [12]. 27 Table 5. Important reactions by the methanogens [12,168]. 27 Table 6. Effects of alkali and alkaline-earth metals on anaerobic digestion [95]. 52 Table 7. Bacterial counts in granules from UASB reactors [31,33]. 91 Table 8. General composition of granules [31]. 96 Table 9. Granule chemical composition [32,33], 96 Table 10. Specific methanogenic activity of various biomass [32,87]. 99 Table 11. Substrates suitable for granule formation. 105 Table 12. Solubility products of metal salts [98]. 111 Table 13. Sucrose feed mixture. 126 Table 14. Beef extract and glucose feed mixture. 127 Table 15. Composition of the beef extract soup base. 128 Table 16. Nutrient (NPK) solution. 128 Table 17. Trace metal solution. 129 Table 18. Ames municipal water analysis. 131 Table 19. ASBR cycle time for 48 and 24-hr HRTs. 133 viii Table 20. Attachment matrices utilized for granulation enhancement. 138 Table 21. Polymer characteristics. 139 Table 22. Coagulants utilized for granulation enhancement. 139 Table 23. Operational parameters routinely tested. 141 Table 24. Reagents used in the COD test. 144 Table 25. Gas chromatography analysis setup. 158 Table 26. Elemental analysis of granules. 165 Table 27. Start-up and granulation summary. 232 Table 28. Summary of specific methanogenic activity experiments. 238 Table 29. Chemical composition of granular and initial seed biomass. 255 Table 30. COD data for the sucrose control test. 286 Table 31. Biogas data for the sucrose control test. 287 Table 32. Volatile acids data for the sucrose control test. 291 Ta...
