The Role of Solvation in Chemical Reaction Kinetics

Emanuel, N.M.; Заиков, Г. Е.; Maizus, Z. K.

doi:10.1016/b978-0-08-022067-3.50010-7

Oxidation of Organic Compounds 1984

DOI: 10.1016/b978-0-08-022067-3.50010-7

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The Role of Solvation in Chemical Reaction Kinetics

N.M. Emanuel¹,

Г. Е. Заиков²,

Z. K. Maizus³

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1992

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“…E°= AH*•0 + RT (lib) and the terms RTty^, and RT<SrE are linear functions with respect to temperature, respectively (Emanuel et al, 1984) ß , = , -tT Equations 7,13, and 14 are the effects of solvent properties on the rate constant, activated energy, and entropy, respectively. Solvent effects on the rate of oxidation of benzaldehyde are discussed in this work.…”

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confidence: 99%

Heterogenized homogeneous catalyst. 6. Effect of solvent on initiation, propagation-termination, decomposition, and an overall heterogeneous-free-radical reaction system

Chou¹,

Yeh²

1992

Ind. Eng. Chem. Res.

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The effects of solvents on reaction rate as well as the rate constants of initiation, propagationtermination, decomposition, and the overall reaction of a heterogeneous-free-radical reaction system were obtained. Both aprotic solvents, such as ethyl acetate, carbon tetrachloride, acetone, and acetonitrile, and protic solvents, such as acetic acid and propionic acid, were used. The main properties of solvents are electrostatic force a{, dispersion force <5S, and specific solvation ET. The results reveal that the properties of solvents significantly affected the activation energy and activation entropy of the reaction steps. The initiation rate of aldehyde oxidation was studied by the inhibitor

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confidence: 99%

Heterogenized homogeneous catalyst. 6. Effect of solvent on initiation, propagation-termination, decomposition, and an overall heterogeneous-free-radical reaction system

Chou¹,

Yeh²

1992

Ind. Eng. Chem. Res.

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The Role of Solvation in Chemical Reaction Kinetics

Cited by 1 publication

References 135 publications

Heterogenized homogeneous catalyst. 6. Effect of solvent on initiation, propagation-termination, decomposition, and an overall heterogeneous-free-radical reaction system

Heterogenized homogeneous catalyst. 6. Effect of solvent on initiation, propagation-termination, decomposition, and an overall heterogeneous-free-radical reaction system

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