An analysis technique has been developed in order to mitigate energy summing due to sequential short-lived α decays from nuclei implanted into a silicon detector. Using this technique, α-decay spectroscopy of the N = 130 isotones 218 Ra (Z = 88) and 220 Th (Z = 90) has been performed. The energies of the α particles emitted in the 218 Ra → 214 Rn and 220 Th → 216 Ra ground-state-to-ground-state decays have been measured to be 8381(4) keV and 8818(13) keV, respectively. The half-lives of the ground states of 218 Ra and 220 Th have been measured to be 25.99(10) μs and 10.4(4) μs, respectively. The half-lives of the ground states of the α-decay daughters, 214 Rn and 216 Ra, have been measured to be 259(3) ns and 161(11) ns, respectively. Fine structure in the α decay of 218 Ra has been observed for the first time, populating the 695-keV 2 + 1 state in 214 Rn. The fine-structure α decay has an α-particle energy of 7715(40) keV and branching ratio b α = 0.123(11)%.