14th International Energy Conversion Engineering Conference 2016
DOI: 10.2514/6.2016-4815
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The Selenide Saga: A Contribution Toward a History of the Selenide Isotope Generator

Abstract: In the mid to late 1970s, the U.S. Department of Energy and its predecessor agencies supported studies on a Selenide Isotope Generator (SIG) that was to power the proposed Jupiter Orbiter Probe Mission (renamed the Galileo mission in 1978). Early studies projected a 1981 generator design with an efficiency of 10.5% (compared to then state-ofpractice efficiencies of under 7%) and a specific power of 6.6 We/kg (compared to then stateof-practice specific powers of 4.2 We/kg). Higher efficiencies were promised in … Show more

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Cited by 4 publications
(2 citation statements)
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“…Thus, the phase transition temperature and the materials' stability are challenging for a high‐performance TE device. Decades witnessed the evolving fabrication of stable liquid‐like thermoelectric devices, such as Ag‐Cu 2 Se‐based candidates in 1982 244–246 . However, the stability of TE module was always restricted by the evaporation of Se at hot side and Cu deposition at cold side in Cu 1.97 Ag 0.03 Se, 247 and this instability leads to the breaking of the module.…”
Section: Module Designingmentioning
confidence: 99%
“…Thus, the phase transition temperature and the materials' stability are challenging for a high‐performance TE device. Decades witnessed the evolving fabrication of stable liquid‐like thermoelectric devices, such as Ag‐Cu 2 Se‐based candidates in 1982 244–246 . However, the stability of TE module was always restricted by the evaporation of Se at hot side and Cu deposition at cold side in Cu 1.97 Ag 0.03 Se, 247 and this instability leads to the breaking of the module.…”
Section: Module Designingmentioning
confidence: 99%
“…Following completion of the MHW Si-Ge RTGs for the Voyager program, the Si-Ge thermoelectric production line at RCA was shut down as interest shifted to a new, higher efficiency generator design for the Galileo mission at 3 M based on an emerging class of copper-silver selenide and gadolinium selenide thermoelectric materials. Subsequent failure of the 3 M ground demonstration unit and disclosure of a deleterious phase transformation in the GdSe n-leg and excessive sublimation of the Cu-Ag-Se p-leg (driven by ionic conduction of the Cu atoms away from the hot junction), led to a Stop Work Order issued by DOE in January 1979 [5]. This left the Galileo program without a viable power source, which led to a restart of the Si-Ge program at GE-Valley Forge in 1979 and development of the higher-power GPHS-RTG for both Galileo and Ulysses.…”
Section: Si-ge Alloys For Rtg Applicationsmentioning
confidence: 99%