The Araçuaí and Ribeira orogens have been studied for decades, and recently, these two orogens were described as the Araçuaí–Ribeira Orogen System. Despite much work investigating this orogenic system, some issues, such as the connection between the two orogens, are still not fully understood. This work aimed to present unpublished Lu-Hf data for the Santa Angélica Intrusive Complex (SAIC) and for the host rocks that are part of the Rio Negro magmatic arc, as well as to present U-Pb ages for these rocks, thus contributing to the understanding of the geological processes that acted in the transition zone between the Araçuaí and Ribeira orogens. Two samples were collected corresponding to the magmatic arc and six samples from the Santa Angélica Intrusive Complex. The zircon grains were separated from the samples and subjected to geochronological (U-Pb) and isotopic (Lu-Hf) analysis by laser ablation-induced coupled plasma mass spectrometry (LA-ICP-MS). The geochronological data for the host rocks indicate a crystallization age of ca. 595 Ma. In contrast, the Hf isotopic data point to at least two magmatic sources, one crust, and one mantle. The geochronological data obtained for the SAIC rocks show three age peaks. The first peak (537 ± 5 Ma) coincides with the process of crustal anatexis and possibly marks the beginning of the generation of magmas associated with post-collisional magmatism. The second peak (510 ± 5 Ma) registers the apex of crystallization of the SAIC, and the third peak of ages (488 ± 7 Ma) marks the upper limit of the magmatism in the SAIC. The SAIC isotopic data point to at least two crustal components and a mantle component (juvenile).