Abstract-Lead-free germanate glasses doped with rare earth ions were synthesized and next studied using excitation and luminescence spectroscopy. Rare [7]. Among several inorganic glass systems, glasses containing cadmium or lead are classified as toxic raw materials and consequently, often eliminated from various practical applications due to their hazardous effect on health and environment. Therefore, lead-and cadmium-free bismuthate glasses are alternatively proposed for potential applications in photonics [8]. The intension of our work was to fabricate rare earth doped lead-free germanate glasses and to examine their optical properties. The previous results indicate that germanate glass in the BaOGa 2 O 3 -GeO 2 system is known as a window for a high energy laser HEL system [9] and its properties can be modified by adding/substituting various glass components [10]. A new type host of germanate bulk glass and glass fiber (GeO 2 -BaO-BaF 2 -Ga 2 O 3 -La 2 O 3 ) singly doped with Tm 3+ ions has been investigated for application as an NIR laser material at 1800 nm [11,12]. Lead-free germanate glasses with the following chemical composition: 60GeO 2 -30BaO -9.5Ga 2 O 3 -0.5Ln 2 O 3 (given in mol%), where Ln = Pr, Eu or Er, were prepared by mixing and melting appropriate amounts of metal oxides of high purity (99.99%, Aldrich Chemical Co.). A homogeneous mixture was heated in a protective atmosphere of dried argon. Mixed reagents were melted for 0.45h at 1200 o C. Excitation and luminescence measurements were performed on a PTI QuantaMaster QM40 coupled with a tunable pulsed optical parametric * E-mail: wojciech.pisarski@us.edu.pl oscillator (OPO), pumped by a third harmonic of a Nd:YAG laser (Opotek Opolette 355 LD). The emission was dispersed by double 200 mm monochromators. The emission spectra were recorded using a multimode UVVIS PMT (R928) and Hamamatsu H10330B-75 detectors. Spectral measurements were carried out with a resolution of 0.1nm. Luminescence lifetimes were determined with accuracy of 1µs. All measurements were carried out at room temperature.Figure 1 presents excitation and luminescence spectra of Pr 3+ ions in lead-free germanate glasses. Excitation spectrum was monitored at em =645nm emission wavelength. The observed bands correspond to transitions originating from the 3 H 4 ground state to the higher-lying 3 P 2 , 1 I 6 , 3 P 1 and 3 P 0 states of trivalent praseodymium. In order to obtain emission spectrum, the glass sample was excited at exc =450nm ( 3 P 2 state of Pr 3+ ).