A typical characteristic of bimodular material beams is that when bending, the neutral layer of the beam does not coincide with its geometric middle surface since the mechanical properties of materials in tension and compression are different. In the classical theory of elasticity, however, this characteristic has not been considered. In this study, a bimodular simply-supported beam under the combination action of thermal and mechanical loads is theoretically analyzed. First, a simplified mechanical model concerning the neutral layer is established. Based on this mechanical model, Duhamel’s theorem is used to transform the thermoelastical problem into a pure elasticity problem with imaginary body force and surface force. In solving the governing equation expressed in terms of displacement, a special solution of the displacement equation is found first, and then by utilizing the stress function method based on subarea in tension and compression, a supplement solution for the displacement governing equation without the thermal effect is derived. Lastly, the special solution and supplement solution are superimposed to satisfy boundary conditions, thus obtaining a two-dimensional thermoelasticity solution. In addition, the bimodular effect and temperature effect on the thermoelasticity solution are illustrated by computational examples.