Article available under the terms of the CC-BY-NC-ND licence (https://creativecommons.org/licenses/by-nc-nd/4.0/) eprints@whiterose.ac.uk https://eprints.whiterose.ac.uk/ Reuse This article is distributed under the terms of the Creative Commons Attribution-NonCommercial-NoDerivs (CC BY-NC-ND) licence. This licence only allows you to download this work and share it with others as long as you credit the authors, but you can't change the article in any way or use it commercially. More information and the full terms of the licence here: https://creativecommons.org/licenses/ Takedown If you consider content in White Rose Research Online to be in breach of UK law, please notify us by emailing eprints@whiterose.ac.uk including the URL of the record and the reason for the withdrawal request. alter the glass structure, with changes identified in both borate and silicate glass networks using Raman 50 spectroscopy. In particular, these glasses were characterised by a significantly higher Q 3 species, which we 51 attribute to Si-O-Zn linkages; addition of ZnO and CaO to the glass composition therefore enhanced glass 52 network polymerisation. The increase in network polymerisation, and the presence of spinel crystallites, were 53 found to increase the glass viscosity of the ZnO / CaO modified base glass; however the viscosities were within 54 the accepted range for nuclear waste glass processing. The ZnO / CaO modified glass compositions were 55 observed to be significantly more durable than the Na 2 O / Li 2 O base glass up to 28 days, due to a combination 56 of the enhanced network polymerisation and the formation of Ca / Si containing alteration layers.