The solubility equation in ternary water-Salt systems Communication 3. Comparison of the second form of the solubility equation with the experimental

Kirgintsev, A. N.; Luk'yanov, A. V.

doi:10.1007/bf00848898

Cited by 2 publications

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“…There is a large amount of information on the activities of water and dissolved salt in the H 2 O–Ca(NO 3 ) 2 system ,,,,,,,, in the literature. The data of various authors are summarized in reference books ,,, and reviews, , among which the article by Oakes et al stands out for its thoroughness.…”

Section: Resultsmentioning

confidence: 99%

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Thermodynamic Properties and Phase Equilibria in the H₂O–Ca(NO₃)₂ System

et al. 2021

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A comprehensive data set of thermodynamic and calorimetric properties of calcium nitrate aqueous solutions, including the heats of dilution, heat capacity, and phase equilibria in a wide temperature and concentration range is thoroughly collected and critically reviewed. A temperature-dependent Pitzer− Simonson−Clegg model is proposed to describe reliably the properties of liquid phase as well as solid−liquid (SLE) and vapor− liquid (VLE) equilibria, including metastable ones, over T = (243.15 to 425.75) K and up to x(Ca(NO 3 ) 2 ) = 0.3. Improved accuracy is obtained as compared to that of earlier models along with incorporating many diverse experimental data types simultaneously.

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Section: Resultsmentioning

confidence: 99%

“…Dashed line (---) represents calculations in the metastable region. Experimental points: red +, ref ; red ○, ref ; black ○, ref ; blue ○, ref ; green ○, ref ; black □, ref ; green ◇, ref .…”

Section: Resultsmentioning

confidence: 99%