The solubility of solids in gases

Phase equilibrium in supercritical CO2 mixtures using a modified Kwak‐Mansoori mixing rule

“…The first efforts to model the phase behavior in systems containing a supercritical fluid were done using the virial EoS (Ewald et al, 1953), but these attempts were not successful. The best results have been obtained using cubic EoS such as SRK and PR (Kurnik et al, 1981).…”

Supercritical Fluid Extraction of Vegetable Materials

“…The paper of Prausnitz [29] shows that the decrease in temperature of gas extraction although results in increase of c/c° quotient, but it is not a sufficient condition to obtaining higher concentration in gas phase. The saturated vapour pressure over the concentrated phase p v or corresponding molar concentration c v in the presence of inert gas, in certain ranges of total pressure significantly decreases with temperature [30]. Therefore the choice of extraction temperature must be a compromise between the influence of temperature on the c/c° and the impact of temperature on the standard c° value.…”

“…Above the relationship allows with some deviations [30], only to describe experimental results obtained in simple, defined two-component system. Nevertheless the dependence allows formulating general rules of conducting gas extraction.…”

“…In 1950s scientists derived an equation of solubility in compressed gases for real systems based on a virial equation of real gas state [27][28][29][30] …”

Sterilization by dry heat

“…However the limitations of this apparatus have already been fully discussed (Ewald and Schmid, 1953;Darmady and Brock, 1954). These investigations showed quite clearly that a number of hot air ovens examined could not be relied upon to provide an even temperature throughout the oven, and indeed might not reach the temperature recorded by the thermometer.…”