The Stability of Perbenzoic Acid Prepared without the Use of Alkali-metal Alcoholates.

Calderwood, H. N.; Lane, L.

doi:10.1021/j150406a010

Cited by 5 publications

References 7 publications

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Epoxidation and Hydroxylation of Ethylenic Compounds with Organic Peracids*One of the laboratories of the Bureau of Agricultural and Industrial Chemistry, Agricultural Research Administration, U. S. Department of Agriculture.

Swern

2011

Organic Reactions

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Oxiranes and alpha‐glycols can be prepared from olefins by a variety of methods. One of the most important and generally applicable of these is the oxidation of ethylenic compounds with organic peracids. Depending on the peracid employed and/or operating conditions either an oxirane or an alpha‐glycol can be obtained in good yield. It is important to note that the oxidation step both in epoxidation and hydroxylation reactions with organic peracids is the conversion of the olefin to the oxirane.

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Epoxidation and Hydroxylation of Ethylenic Compounds with Organic Peracids*One of the laboratories of the Bureau of Agricultural and Industrial Chemistry, Agricultural Research Administration, U. S. Department of Agriculture.

Swern

2011

Organic Reactions

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TheBaeyer‐VilligerOxidation of Aldehydes and Ketones

Hassall

2011

Organic Reactions

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In 1899, Bayer and Vlliger showed that the oxidation of alicyclic ketones, menthone, tetrahydrocarvone, and camphor with permono‐sulfuric acid led to the formation of lactones. Further studies using a variety of ketones or aldehydes and hydrogen peroxide or peracids in various media have established that the oxidation is of wide applicability. The oxidation, the Baeyer‐Villiger reaction, is the subject of this review. As the oxidation normally employs mild conditions, gives reasonable yields, and shows a high degree of selectivity, it has proved useful in a variety of both synthetic and degradative studies. Recent investigations have led to a better definition of favorable experimental conditions and have extended the scope of the reaction.

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Use of perbenzoic acid in analysis of unsaturated compounds. I. Preparation and stability of solutions of perbenzoic acid

1947

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The preparation of perbenzoic acid has been investigated in a n attempt to obtain standard solutions of perbenzoic acid suitable for the amlyszk of unsaturated compounds. Some modifiations of the procedure given by Braun for the preparation of a solution of perbenzoic acid in a n organic solvent are recommended. A study has been made of the stability of solutions of perbenzoic acid in chloroform and in benzene. Benzene or benzene‐chloroform mixtures are recommended as solvents for perbenzoic acid. Chloroform solutions of perbenzoic acid which do not contain inhibitors for decomposition have been found to be definitely undesirable in analytical work because perbenzoic acid catalyzes the decomposition of chloroform by oxygen. construction Finance Corporation, in connection with the Government Synthetic Rubber Program.

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The Stability of Perbenzoic Acid Prepared without the Use of Alkali-metal Alcoholates.

Cited by 5 publications

References 7 publications

Epoxidation and Hydroxylation of Ethylenic Compounds with Organic Peracids*One of the laboratories of the Bureau of Agricultural and Industrial Chemistry, Agricultural Research Administration, U. S. Department of Agriculture.

Epoxidation and Hydroxylation of Ethylenic Compounds with Organic Peracids*One of the laboratories of the Bureau of Agricultural and Industrial Chemistry, Agricultural Research Administration, U. S. Department of Agriculture.

TheBaeyer‐VilligerOxidation of Aldehydes and Ketones

Use of perbenzoic acid in analysis of unsaturated compounds. I. Preparation and stability of solutions of perbenzoic acid

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