The Stereochemistry of the Mechanical Bond

Bruns, Carson J.

doi:10.1002/9781119044123.ch5

The Nature of the Mechanical Bond 2016

DOI: 10.1002/9781119044123.ch5

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The Stereochemistry of the Mechanical Bond

Carson J. Bruns¹

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2020

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Macrocyclic Hamilton receptor-shuttling dynamics in [2]rotaxanes

Douarre

Martí‐Centelles

Rossy

et al. 2020

Supramolecular Chemistry

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Electronic Supplementary Information (ESI) available: experimental procedures, characterization data of 1, 2, and 4 (1 H, 13 C, VT NMR) and molecular modeling structures of rotaxanes 1, 7, 8 and 9. Macrocyclic Hamilton receptor-shuttling dynamics in [2]rotaxanes Inherent movement of a macrocycle comprising a multi-site hydrogen bonding Hamilton-type receptor in a series of [2]rotaxanes was investigated by dynamic and VT NMR. In these rotaxanes the varying nature and number of hydrogenbond motifs and stations on the molecular axles influenced ring dynamics. Triazole stations interact selectively by hydrogen bonding with the isophthalamide amide bonds present in the Hamilton macrocycle and fast shuttling (72 kHz at 25 °C) was observed in a two station variant.

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Macrocyclic Hamilton receptor-shuttling dynamics in [2]rotaxanes

Douarre

Martí‐Centelles

Rossy

et al. 2020

Supramolecular Chemistry

View full text Add to dashboard Cite

show abstract

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The Stereochemistry of the Mechanical Bond

Cited by 1 publication

References 483 publications

Macrocyclic Hamilton receptor-shuttling dynamics in [2]rotaxanes

Macrocyclic Hamilton receptor-shuttling dynamics in [2]rotaxanes

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