In the present study, microstructure and mechanical properties of a new b-metastable TiZrAlV prepared via thermomechanical processing (TMP) treatments have been studied. An excellent combination of ultimate tensile strength (s b % 1 630 MPa) and ductility (e f % 6.6%) has been achieved in the alloy after cold rolling, thermal annealing (665 C/1 h), and two-step aging (650 C/ 0.5 h þ 450 C/2 h). This is attributed to the formation of a refined b microstructure with grain size of %10 mm and a multi-modal-laminated structure that consists of large primary a p grains (2 mm, 9.5 vol %) and coarse a precipitates (300 nm, 21 vol%) and fine a platelets (50 nm, 65 vol%). The fine a platelets contribute to high strength while the large primary a p grains and the refined b grain size provide ductility.b-Metastable titanium alloys have been considered attractive materials for widespread applications, such as aircraft design and automotive industries, because of the combination of high strength-to-density ratio (50-280 MPa cm 3 g À1 ), good corrosion resistance, and excellent fatigue property (e.g., HCF strength of 500-650 MPa at 10 7 cycles). [1,2] Mechanical properties of b-metastable Ti alloys are usually enhanced by the precipitation of fine secondary a phase using aging treatment, which leads to increased strength and decreased ductility. [1,2] However, at strength levels above 1 300 MPa, their practical applications (e.g., the material's service lifetime) have been limited by low ductility. [3] It is, therefore, significant to enhance the ductility of high-strength b-Ti alloys for practical applications, as the enhanced ductility can enhance the material's resistance to fatigue and extend the material's service lifetime. [4] Usually, the ductility of b-Ti alloys is controlled not only by b grain size but also by the morphology and distribution of a precipitates. [5,6] Previous studies show that a combination of a fine-grain b microstructure and the fine and uniform precipitation of a precipitates can lead to an exceptional combination of high strength and reasonable ductility in TIMETAL-LCB and b-21S alloys. [3,7] Recently, a multi-modal-laminated structure, [8][9][10][11][12] consisting of large a p grains and fine a precipitates or of coarse and fine a precipitates, has been extensively reported to achieve an excellent balance of strength (ultimate strength > 1 500 MPa) and ductility (elongation to failure > 6%) in many Ti alloys.A new b-metastable high-strength TiZrAlV alloy has been recently designed for aerospace applications. [13][14][15] Previous studies demonstrate that the chemical properties of Zr and Ti are similar, these two metals have a stronger solid solution strengthening response and the b transition temperature of the ZrTi binary alloys can be modulated by varying the element contents. [13,16,17] These favorable conditions may contribute to develop a new TiZrAlV alloy with excellent mechanical properties. However, the relationship between the microstructure and mechanical properties of this new TiZrAlV...