The Structure of Hydrotris(imidazolyl)boratothallium(I) - the First Structurally Authenticated Tris(imidazolyl)borate Metal Complex

Janiak, Christoph; Röhr, Caroline; Temizdemir, Savaş

doi:10.1002/(sici)1521-3749(200006)626:6<1265::aid-zaac1265>3.0.co;2-f

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Cited by 23 publications

References 7 publications

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Pyridylborates as a New Type of Robust Scorpionate Ligand: From Metal Complexes to Polymeric Materials

2016

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The importance of scorpionate ligands in modern coordination chemistry continues to increase, because of their outstanding versatility, tunability and user-friendliness. Herein, we provide a short overview of recent developments in the classes of scorpionate ligands, derived from pyrazoles, triazoles, imidazoles, oxazolines, thioimidazoles and other similar systems, followed by an in-depth discussion of a new type of ro- Classes of Scorpionate LigandsScorpionate ligands [1] are facially coordinating tridentate chelates, which have evolved into one of the most useful and [a]

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Pyridylborates as a New Type of Robust Scorpionate Ligand: From Metal Complexes to Polymeric Materials

2016

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A Manganese(II) Coordination Polymer with Ditopic Bis(pyrazol‐1‐yl)borate Bridges

Morawitz¹,

Bolte²,

Lerner³

2008

Zeitschrift anorg allge chemie

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The synthesis and characterization of the ditopic bis(pyrazol‐1‐yl)borate ligand Li2[p‐C6H4(B(C6F5)pz2)2] is reported (pz = pyrazol‐1‐yl). Compared to the corresponding t‐butyl derivative Li2[p‐C6H4(B(t‐Bu)pz2)2], the C6F5‐substituted scorpionate is significantly more stable towards hydrolysis. Reaction of Li2[p‐C6H4(B(C6F5)pz2)2] with two equivalents of MnCl2 leads to the formation of coordination polymers {(MnCl2)2(Li(THF)3)2[p‐C6H4(B(C6F5)pz2)2]}∞ featuring penta‐coordinate MnII ions chelated by one bis(pyrazol‐1‐yl)borate fragment and further bonded to three chloride ions. Two of the three chloride ions are also coordinated to a neighbouring MnII ion; the third chloro ligand is shared between the MnII centre and a Li(THF)3 moiety.

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[B(O–C₆H₄–CN)₄]^– based Silver and Copper Coordination Polymers

Lund

Harloff

Schulz

et al. 2014

Zeitschrift anorg allge chemie

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The Structure of Hydrotris(imidazolyl)boratothallium(I) - the First Structurally Authenticated Tris(imidazolyl)borate Metal Complex

Cited by 23 publications

References 7 publications

Pyridylborates as a New Type of Robust Scorpionate Ligand: From Metal Complexes to Polymeric Materials

Pyridylborates as a New Type of Robust Scorpionate Ligand: From Metal Complexes to Polymeric Materials

A Manganese(II) Coordination Polymer with Ditopic Bis(pyrazol‐1‐yl)borate Bridges

[B(O–C₆H₄–CN)₄]^– based Silver and Copper Coordination Polymers

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The Structure of Hydrotris(imidazolyl)boratothallium(I) - the First Structurally Authenticated Tris(imidazolyl)borate Metal Complex

Cited by 23 publications

References 7 publications

Pyridylborates as a New Type of Robust Scorpionate Ligand: From Metal Complexes to Polymeric Materials

Pyridylborates as a New Type of Robust Scorpionate Ligand: From Metal Complexes to Polymeric Materials

A Manganese(II) Coordination Polymer with Ditopic Bis(pyrazol‐1‐yl)borate Bridges

[B(O–C6H4–CN)4]– based Silver and Copper Coordination Polymers

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Product

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[B(O–C₆H₄–CN)₄]^– based Silver and Copper Coordination Polymers