Abstract. The 2*Si level scheme up to 14.5 MeV excitation energy is reevaluated using information from two preceding papers. It consists of approximately 250 levels which are almost completely characterized according to the quantum numbers 1, re, T of the levels. The properties of positive-parity states are compared to the predictions of shell model calculations within the complete s-d basis space using the unified s-d shell Hamiltonian. A spectrum of 48 experimental T = 1 states between 9.3 and 16 MeV is reproduced with a rms deviation of only 150 keV. A calculation of radiative widths and 7-decay modes which uses free-nucleon 9-factors yields excellent agreement with experiment and confirms that quenching of M1 transitions is only marginal in 2ssi. The detailed shell model analysis of the T = 0 spectrum is extended to the limiting energy where T = 1 wave function admixtures, not contained in the theory, become important experimentally. This happens at 6-8 MeV above the yrast state, depending on the spin value. Altogether it appears that a spectrum of 171 levels below 14.5 MeV, which have positive or unassigned parity, is almost completely accounted for by the model. Apparent intruder states from outside the s-d shell space are observed at Ex=lO945keV (U=4 +) and 12860 keV (U= 6 +) and are interpreted as members of a K S = 0 + rotational band.