The structures of barium D-galactarate monohydrate and calcium D-galactarate tetrahydrate

Zinc Saccharate: A Robust, 3D Coordination Network with Two Types of Isolated, Parallel Channels, One Hydrophilic and the Other Hydrophobic

“…The iodine content was determined by adding an excess of sodium thiosulfate and back titrating with potassium iodate. Yield; elemental analysis (%) calcd for [Zn(C 6 . Keywords: carbohydrates · coordination polymer · structure elucidation · zinc…”

“…In 1998 it was shown that copper(ii) saccharate has a linear polymeric chain structure, [2] and the structures of the potassium and calcium salts were described earlier. [3] The structures of a number of Group 1 and 2 metal derivatives of galactaric acid (also known as mucic acid) were reported (Na, [4] K, [4] Mg, [5] Ca [6] and Ba [6] ). Galactaric acid is presently cheaper than saccharic acid, but is not chiral.Crystals of hydrated zinc saccharate, [Zn(C 6 H 8 O 8 )]· % 2 H 2 O (1), suitable for single crystal X-ray diffraction studies were obtained directly from an aqueous solution containing potassium hydrogen saccharate and zinc acetate.…”

X-ray powder diffraction data for calcium galactarate tetrahydrate CaC6H8O8·4H2O and Rietveld refinement of the crystal structure

“…Initial lattice parameters, atomic coordinates and isotropic displacement parameters were taken from the single crystal determination reported by Sheldrick et al (1989). In the full-profile refinement the following parameters were refined; one scale factor; one zero- (16) 3.6(2) 9.1(6) 8.5(7) 6.5(5) 1.1(4) 9.1(4) 6.0(4) 3.5(9) 1-7(8) 0.8(6) …”

“…Atomic coordinates and isotropic displacement parameters obtained from single crystal (Sheldrick et al, 1989) and powder data are compared in Table II. …”

First sphere coordination of divalent metal cations by cyclodextrin: structure of the β-cyclodextrin–calcium chloride–water (1/2/11.25) compound

“…7). Eightfold coordination of the calcium is common and has been found in calcium salts of mono-and disaccharides such as calcium Dgalactarate, tetrahydrate (Sheldrick, Mackie & Akrigg, 1989) and the calcium bromide complexes of lactose, galactose and inositol (Bugg & Cook, 1972), the calcium coordination being achieved by four, five or six hydroxyl groups of different saccharide molecules and by water molecules.…”