The structures of Li5BiO5 and Li5SbO5 from powder neutron diffraction

Synthesis and crystal structure investigations of ternary oxides in the Na–Pu–O system

“…These layers are linked with neighboring sheets by Na atoms in the a-direction (3 layers per unit cell) resulting in the formation of the three dimensional structure. The crystal structure of Na 5 PuO 5 is similar to that of Li 5 SbO 5 [21].…”

Computer-aided design of metal chalcohalide semiconductors: from chemical composition to crystal structure

“…The remaining compound, Cd 5 S 4 Cl 2 , adopts the same structure type as Li 5 BiO 5 . 47 However, this substitution is rejected by the structure prediction algorithm on the basis that the resulting formula is not charge neutral – the structure we find is partially inverted in terms of anion/cation occupancy.…”

Preparation and Crystal Structure of a New Lithium Bismuth Oxide: LiBiO3

“…Some of these compounds contain pentavalent bismuth which is an unusual oxidation state for bismuth. There are three known lithium bismuth oxides containing pentavalent bismuth: Li 3 BiO 4 (6), Li 7 BiO 6 (7), and Li 5 BiO 5 (8). However, LiBiO 3 has not been previously reported.…”