The possible use of high-Mg host rocks, such as serpentinite and pyroxenite, from the Aganozero chromium ore deposit and serpentinite from the Ozerki soapstone deposit, Republic of Karelia, for the production of heatinsulating building materials, ceramic pigments and filters for purification of technogenous solutions is assessed. The results of analysis of the mineralogical compositions of serpentinites and pyroxenite, as well as the physico-mechanical properties (strength, heat conductivity, shrinkage upon roasting, moisture resistance, etc.) and structural characteristics of the ceramic and heat-insulating materials produced on their basis are reported.