A systematic analysis of experimentally, solar parameters of photogalvanics has been studied for performance analysis using the D-R-S (Dye-Reductant–Surfactant) system as alizarin cyanine green–EDTA- sodium stearate system. A H shaped photogalvanic system was used under investigation for innovative results. Different scientific instruments were used in methodology set up i.e., microammeter, digital pH meter, and light source (200 W Philips bulb), multi-meter, calomel electrode (saturated), Pt electrode, and circuit key. The photogalvanic parameters were studied using H cell glass tubes as PP (Photo-Potential), PC (Photo-Current), CF (Conversion Efficiency), FF (Fill-Factor) & PA (Performance Analysis). The experimental results are as follows: 733.0 mV, 477.0 mA, 1.7984%, 0.2640 and 180.0 minutes. The observed electrical outputs are better than previously published electrical outputs with respect to alizarin cyanine green, EDTA, and sodium stearate system.