The
recovery of energy from organic waste opens a chance to promote
the renewable energy production, reducing the use of fossil-based
fuels. This study is focused on the virtuous valorization of swine
manure, which is conventionally used as a fertilizer. An integrated
valorization process of swine manure via transesterification
and CO2-assisted pyrolysis was suggested to maximize the
recovery of energy-intensive and value-added products, such as biodiesel,
biochar, and syngas. Lipid fraction in the swine manure was transformed
into biodiesel through thermally induced transesterification. The
yield of biodiesel was ≥94 wt % (based on the lipid content)
in the existence of silica and swine manure biochar at 400 and 220
°C, respectively. The biochar acted as a porous medium and alkaline
catalyst for transesterification. The residual solid after transesterification
(i.e., lipid-extracted swine manure) was valorized
with pyrolysis. CO2 was fed as a co-reactant to carry out
the process in a more sustainable manner. In the presence of CO2, the enhancement of CO production was observed because of
the homogeneous reactions of CO2 with gaseous pyrogenic
products derived from swine manure, compared to pyrolysis in a N2 atmosphere. To expedite the reaction rates affecting the
homogeneous reaction, a Ni/SiO2 catalyst was adopted. Syngas
formations were significantly enhanced through the synergistic effects
of CO2 and the Ni/SiO2 catalyst. All experimental
observations signified that swine manure could be considered a useful
resource that can be valorized into value-added fuels and chemicals.