upon Tyne NEI 7RU. U K S U M M A R YVirtually all of the indigenous sulphate (SO,) in a range of UK soils with moderately high pH values (> 6) was found to be present in the soil solution and, as a consequence, was highly susceptible to leaching. For acid soils containing adsorbed SO,, the extractability of SO, in NaCl and CaCI, solutions was dependent on both the ionic strength and cation species. Addition of small amounts (< -1 0 -2~) of either NaCl or CaCI, actually decreased the amount of SO, extracted, but SO, extractability increased sharply with concentrations of NaCl or CaCI, higher than about 0.1 M. At a similar ionic strength, more SO, was extracted by NaCl than CaCI,. Sequential extraction with 1 M NaCl removed essentially all of the absorbed SO,. The release characteristics of SO, were very different to those of phosphate and this difference in behaviour is not easily reconciled with the view that SO, is chemisorbed, as is phosphate. Except for a few acid soils with high oxide contents, the capacity of the soils to adsorb added SO, was quite small. None of the soils with pH values higher than 6 adsorbed a significant amount SO,. The results raise questions regarding the efficiency of SO,-containing fertilizers in correcting and preventing S deficiency in situations where leaching is important. *Present address: Agriculture Canada Research Station, PO Box 1030, Swift Current, Saskatchewan S9H 3x2. Canada.