2003
DOI: 10.1080/0095897021000050969
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The Synthesis and Characterization of a Novel ( E , E )-Dioxime and its Mono- and Heterotrinuclear Complexes Containing an 18-Membered Dioxadithiadiazamacrocycle

Abstract: The novel (E,E )-dioxime, 5,6:17,18-dibenzo-11,12-(4 0 -nitrobenzo)-2,3-bis(hydroxyimino)-7,16-dithia-10,13-dioxa-1,4-diazacyclooctadecane) (H 2 L), has been synthesized from reaction of (E,E )-dichloroglyoxime (1) with 2,3:14,15-dibenzo 8,9-(4 0 -nitrobenzo)-4,13-dithia-7,10-dioxa-1,16-diazahegzadecane (2). The mononuclear Co(III) complex (4) of this dioxime was prepared by oxidation of the cobalt (II) complex. The BF þ 2 -capped Co(III) complex (5) was synthesized by using a precursor Co(III) complex and bor… Show more

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Cited by 4 publications
(1 citation statement)
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“…The past decade has included studies on their syntheses and characterization [10,11], preparation of their mono-nuclear [12][13][14], homo- [15] and hetero-polynuclear [16,17], and polymeric metal complexes [18][19][20]. Flourescence [21], optical [22][23][24], biological [25,26], electrochemical [27][28][29], and thermal properties [30,31] have been of particular interest.…”
Section: Introductionmentioning
confidence: 99%
“…The past decade has included studies on their syntheses and characterization [10,11], preparation of their mono-nuclear [12][13][14], homo- [15] and hetero-polynuclear [16,17], and polymeric metal complexes [18][19][20]. Flourescence [21], optical [22][23][24], biological [25,26], electrochemical [27][28][29], and thermal properties [30,31] have been of particular interest.…”
Section: Introductionmentioning
confidence: 99%