The Synthesis and Complex Formation of 5,6-Dihydrocyclopent [f, g] Acenaphthylene-1,2-Dione Dioxin

Gül, Ahmet; roĝlu, Özer Bek

doi:10.1080/00945718208056024

Cited by 43 publications

(1 citation statement)

References 12 publications

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“…[1] Most of the work carried out so far has been on symmetrically disubstituted [2,4] glyoximes and only partly on mono-substituted ones. [1] Most of the work carried out so far has been on symmetrically disubstituted [2,4] glyoximes and only partly on mono-substituted ones.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Complex Formation of Substituted Amino‐2‐naphthylglyoximes of Unsymmetricalvic‐Dioximes

Yıldırım

Pekacar

Uçan

2003

Synthesis and Reactivity in Inorganic and Metal-Organic Chemist

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anti-2-Naphthylchloroglyoxime has been synthesized by chlorination of anti-2-naphthylglyoxime. Reaction with aryl-or arylalkylamines in EtOH between 15°C and 20°C gives unsymmetrical vic-dioximes, namely, anilino-2-naphthylglyoxime (L 1 H 2 ), benzylamino-2-naphthylglyoxime (L 2 H 2 ), p-toluidino-2-naphthylglyoxime (L 3 H 2 ) 1-naphthylamino-2naphthylglyoxime (L 4 H 2 ). The Ni(II) and Cu(II) complexes of these ligands are square-planar while the Co(II) complexes are octahedral with water molecules as axial ligands. 1 H NMR, IR and elemental analyses data of the complexes and ligands are discussed.

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Section: Introductionmentioning

confidence: 99%

Synthesis and Complex Formation of Substituted Amino‐2‐naphthylglyoximes of Unsymmetricalvic‐Dioximes

Yıldırım

Pekacar

Uçan

2003

Synthesis and Reactivity in Inorganic and Metal-Organic Chemist

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Syntyhesis of 1,2,4,5‐Tetrazino[1,6‐a: 4,3‐a′]diquinoxaline

Koçak¹,

Berkâroǧlu²

1984

Helvetica Chimica Acta

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SummaryA new one-step synthesis of 2(1H)-quinoxalinone oxime (3) from (1,2-benzenediamine (1) and s-trans-chloroethanedial dioxime (2) is described. This oxime is converted into a new heterocyclic compound, 1,2,4,5,-tetrazino[ 1,6-a :4,3-af]diquinoxaline (4), by the template effect of Co(I1) and Ni(I1) ions.Introduction. ~ The aid of metal ions as templates to direct the steric course of condensations for heterocyclic compounds has been reported [ 1-31. A metal ion brings together the reactants by coordination and the reaction takes place in a series of stereochemically controlled steps. The template effect also enables the synthesis of some compounds which are not otherwise accessible. We have investigated the structures and transition metal complexes of diaminoglyoxime and its substituted derivatives [5-121. A completely conjugated 12-membered macrocycle, dibenzo[b,h]-1,4,7,1O-tetraazacyclododecyne, has been obtained by refluxing its octahydrodioxime derivative in dimethyl sulfoxide [ 131.A one-step preparation of 2(1H)-quinoxalinone oxime (3) is described, and a new heterocyclic ring system, 1,2,4,5-tetrazino[ 1,6-a :4,3-a']diquinoxaline, obtained a template reaction was introduced.

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Synthesis and Complexation of 1,2‐Bis[(monoaza[15]crown‐5)‐N‐yl]glyoxime. Crystal Structure of (1,2‐Bis[(monoaza[15]crown‐5)‐N‐yl]glyoximato)palladium(II)

Ahsen

Musluoğlu

Gürek

et al. 1990

Helvetica Chimica Acta

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The Synthesis and Complex Formation of 5,6-Dihydrocyclopent [f, g] Acenaphthylene-1,2-Dione Dioxin

Cited by 43 publications

References 12 publications

Synthesis and Complex Formation of Substituted Amino‐2‐naphthylglyoximes of Unsymmetricalvic‐Dioximes

Synthesis and Complex Formation of Substituted Amino‐2‐naphthylglyoximes of Unsymmetricalvic‐Dioximes

Syntyhesis of 1,2,4,5‐Tetrazino[1,6‐a: 4,3‐a′]diquinoxaline

Synthesis and Complexation of 1,2‐Bis[(monoaza[15]crown‐5)‐N‐yl]glyoxime. Crystal Structure of (1,2‐Bis[(monoaza[15]crown‐5)‐N‐yl]glyoximato)palladium(II)

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