The synthesis and crystal structure of bis(2-(benzo[d]thiazol-2-yl)-5-methylbenzen-1-ido-κ² C,N)-(N,N′-diethyldithiocarbamato-κ² S,S′)iridium(III), C₃₃H₃₀N₃S₄Ir

Abstract

C33H30N3S4Ir, monoclinic, P21/c (no. 14), a = 11.6429(10) Å, b = 10.9111(10) Å, c = 24.234(2) Å, β = 93.2890(10)°, V = 3073.6(5) Å3, Z = 4, Rgt(F) = 0.0198, wRref(F2) = 0.0507, T = 273(2) K.

Crystal structure of 1-[3-(trifluoromethyl)cinnamoyl]-3-(pyridin-2-yl-κN)pyrazole-κ2 N-bis(2-phenylpyridinato-k2 C,N)iridium(III) hexafluorophosphate complex, [C40H28F3IrN5O]PF6

“…The archetypal Ir(III) phenylpyridine based complexes are widely employed in OLEDs and LEECs due to their high quantum yields, stability and facile colour tunability [15,16]. The photophysical properties of these Ir(III) complexes can be tuned by utilising different ancillary ligands [17,18] and also by employing various substituents on the phenylpyridine moieties and ancillary ligands [19,20]. The photophysical properties of Ir(III) phenylpyridine complex with pyridylpyrazole moieties as an ancillary ligand has been studied for LEECs application [21].…”