The Synthesis and Purification of Ethers

A novel method for synthesis of benzyl alkyl ethers using vanadium-based metal complex catalysts

“…The structure of the resulting benzyl alkyl ethers was confirmed by the spectral data and by comparing with the known samples and reference data: benzyl methyl ether, 1 (yield 85%) [7], benzyl ethyl ether, 6 (yield 26%), benzyl propyl ether, 7 (yield 27%) [8], benzyl 2 propyl ether, 8 (yield 32%) [9], benzyl butyl ether, 9 (yield 34%) [7], benzyl amyl ether, 10 (yield 24%) [10], dibenzyl ether, 15 (yield 62%) [11][12], benzyl cyclohexyl ether, 18 (yield 64%) [13].…”

Hydrated ferric perchlorate, Fe(ClO4)3.XH2O in organic synthesis. A short review

“…The common method for the conversion of alcohols to ethers consists of the reaction of metal salts of alcohols with different alkylating agents in the presence of various catalysts [10][11][12][13][14]. Condensation of alcohols or their salts with aldehydes, olefins and alkyloxides [18], dialkyl phosphates [19] and alcohols [20,21] have also been reported.…”

Synthese und Struktur von Tetrachloro[4-tert-butyl-2(diphenylphosphanyl-κP-methyl)phenolato-κO]tantal(V), ein neuartiger TaV-Komplex mit einem chelatisierenden Aryloxyphosphanliganden

“…Zur Synthese des gewu È nschten hemilabilen Sauerstoff-Phosphor-Liganden wird 4-tert-Butylanisol [7] einer Chlormethylierung unterworfen [8], und das Produkt dieser Reaktion metathetisch zum gewu È nschten Phosphan-funktionalisierten Anisol 1 umgesetzt (Schema 2).…”