The synthesis and topochemical polymerization of <i>o</i>-carborane-based diacetylene macrocycles

Fu, Meigui; Yuan, Shuai; Qu, Qi; Yuan, Yaofeng; Lin, Caixia; Geng, Yanhou

doi:10.1039/d3nj03491g

New J. Chem.

2023

DOI: 10.1039/d3nj03491g

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The synthesis and topochemical polymerization of o-carborane-based diacetylene macrocycles

Meigui Fu,

Shuai Yuan,

Qi Qu

et al.

Abstract: A kind of o-carborane-based macrocycles were synthesized via oxidative coupling of acetyleneterminated o-carborane precursors. The single crystal X-ray diffraction analysis unambiguously revealed their unique porous supramolecular structures, which displayed micropore...

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2024

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Cited by 3 publications

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Topochemical cross-linking of diacetylene in a highly interpenetrated three-dimensional covalent organic framework

Liu,

Chen,

Zhao

et al. 2024

Chem. Commun.

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Topochemical cross-linking of diacetylene in a highly interpenetrated three-dimensional covalent organic framework

Liu,

Chen,

Zhao

et al. 2024

Chem. Commun.

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Synthesis of C-Mercuro Derivatives of ortho-Carborane. Crystal Structure of Bis(2-phenyl-ortho-carboran-1-yl)mercury

Anufriev,

Timofeev,

Nasyrova

et al. 2024

Russ. J. Inorg. Chem.

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Synthesis of C-mercuro derivatives of ortho-carborane. Crystal structure of bis(2-phenyl-ortho-carboran-1-yl)mercury

Anufriev,

Timofeev,

Nasyrova

et al. 2024

Žurnal neorganičeskoj himii

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Many carborane derivatives, first synthesized during the rapid development of this field of chemistry in the 60s of the last century, remained completely uncharacterized by modern spectral and structural methods. In this work, a series of C-mercuro derivatives of ortho-carborane 1-PhHg-2-Ph-1,2-C2B10H10 and (2-R-1,2-C2B10H10)2Hg (R = H, Me, Ph) were newly synthesized and characterized by NMR spectroscopy. The molecular crystal structure of bis(2-phenyl-ortho-carboran-1-yl)mercury was determined by single crystal X-ray diffraction.

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The synthesis and topochemical polymerization of o-carborane-based diacetylene macrocycles

Abstract: A kind of o-carborane-based macrocycles were synthesized via oxidative coupling of acetyleneterminated o-carborane precursors. The single crystal X-ray diffraction analysis unambiguously revealed their unique porous supramolecular structures, which displayed micropore...

Cited by 3 publications

References 33 publications

Topochemical cross-linking of diacetylene in a highly interpenetrated three-dimensional covalent organic framework

Topochemical cross-linking of diacetylene in a highly interpenetrated three-dimensional covalent organic framework

Synthesis of C-Mercuro Derivatives of ortho-Carborane. Crystal Structure of Bis(2-phenyl-ortho-carboran-1-yl)mercury

Synthesis of C-mercuro derivatives of ortho-carborane. Crystal structure of bis(2-phenyl-ortho-carboran-1-yl)mercury

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