The Synthesis of 9,10‐Dihydro‐9,10‐(methaniminomethano)anthracene and N‐Protected Derivatives via Double Reductive Amination.

Abstract

2005Multi-membered N-heterocycles R 0690The Synthesis of 9,10-Dihydro-9,10-(methaniminomethano)anthracene and N-Protected Derivatives via Double Reductive Amination. -A practical and efficient route to the title compound (X) and several N-protected derivatives via a double reductive amination of cis-anthracene-9,10-dialdehyde (V) is developed. -(STOY, P.; RUSH, J.; PEARSON*, W. H.; Synth.