The Synthesis of Poly(Vinyl Alcohol) Grafted with Fluorinated Protic Ionic Liquids Containing Sulfo Functional Groups

Glińska, Patrycja; Wolan, Andrzej; Kujawski, Wojciech; Rynkowska, Edyta; Kujawa, Joanna

doi:10.3390/molecules26144158

Cited by 3 publications

(2 citation statements)

References 33 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The use of poly(vinyl alcohol) (PVA) as a "substrate" for preparing a grafted protic polyionic liquid for proton exchange membranes (PEMs) for fuel cell applications. 198 They activated PVA with LiCl in DMA (dimethylacetamide), and then acetylated using 2-chloroacetic anhydride in the presence of imidazole. This yielded imidazole acetate modification of the hydroxyl groups.…”

Section: Graftingmentioning

confidence: 99%

“…Urea-functionalized poly(ionic liquid) photonic spheres Poly(dication 1,6-di(3-vinylimidazolium)hexane bromide) Picric acid, 4-nitrophenol, 2,4,6-trinitroresorcinol, 2,4-dinitrophenol, and 1,3,5-trinitrotoluene 2019 770 Coumarin-based fluorescent molecularly imprinted poly(ionic liquid) Poly(7-(diethylamino)-2-oxo-2H-chromene-3-carboxylic acid)/poly(1,4-butanediyl-3,3′-bis-l-vinylimidazolium dihexafluorophosphate)/Poly(EGDMA), EGDMA = ethylene glycol dimethacrylate 4-Nitrophenol with a detection limit of 0.5 nM 2020 771 Polymerizable imidazolium-based ionic liquids membrane Poly(1-(2-methacryloyloxy)ethyl-3-butylimidazolium (ILTFSI)vinyl-3-butylimidazolium tetrafluoroborate-co-acrylate-terminated hyperbranched polymer) Human motion with a low response time of 200 ms 2021 276Lignin-reinforced thermoresponsive poly(ionic liquid) hydrogelPoly(1-vinyl-3-butylimidazolium bromide-co-vinyl-modified lignin (v-lignin)-co-acrylamide)Human movement with a high gauge factor (1.37) and rapid response rate(198 ms) 2021 783 Self-healable, recyclable, and ultrastrong adhesive ionogel Poly(1-vinyl-3-butylimidazolium tetrafluoroborate) Bending of fingers 2021 218 Thermal sensors Recyclable conductive colloidal polymer Poly(2-(6-(3-(6-methyl-4-oxo-1,4-dihydropyrimidin-2-yl)ureido)hexylcarbamoyloxy) ethyl methacrylate-co-1-vinyl-3-ethyl-imidazolium bromide) /doi.org/10.1021/acs.chemrev.3c00429 Chem. Rev.…”

mentioning

confidence: 99%

See 1 more Smart Citation

Polymerized and Colloidal Ionic Liquids─Syntheses and Applications

Li,

Yan,

Texter

2024

Chem. Rev.

View full text Add to dashboard Cite

The breadth and importance of polymerized ionic liquids (PILs) are steadily expanding, and this review updates advances and trends in syntheses, properties, and applications over the past five to six years. We begin with an historical overview of the genesis and growth of the PIL field as a subset of materials science. The genesis of ionic liquids (ILs) over nano to meso lengthscales exhibiting 0D, 1D, 2D, and 3D topologies defines colloidal ionic liquids, CILs, which compose a subclass of PILs and provide a synthetic bridge between IL monomers (ILMs) and micro to macroscale PIL materials. The second focus of this review addresses design and syntheses of ILMs and their polymerization reactions to yield PILs and PIL-based materials. A burgeoning diversity of ILMs reflects increasing use of nonimidazolium nuclei and an expanding use of step-growth chemistries in synthesizing PIL materials. Radical chain polymerization remains a primary method of making PILs and reflects an increasing use of controlled polymerization methods.Step-growth chemistries used in creating some CILs utilize extensive cross-linking. This cross-linking is enabled by incorporating reactive functionalities in CILs and PILs, and some of these CILs and PILs may be viewed as exotic cross-linking agents. The third part of this update focuses upon some advances in key properties, including molecular weight, thermal properties, rheology, ion transport, self-healing, and stimuli-responsiveness. Glass transitions, critical solution temperatures, and liquidity are key thermal properties that tie to PIL rheology and viscoelasticity. These properties in turn modulate mechanical properties and ion transport, which are foundational in increasing applications of PILs. Cross-linking in gelation and ionogels and reversible step-growth chemistries are essential for self-healing PILs. Stimuli-responsiveness distinguishes PILs from many other classes of polymers, and it emphasizes the importance of segmentally controlling and tuning solvation in CILs and PILs. The fourth part of this review addresses development of applications, and the diverse scope of such applications supports the increasing importance of PILs in materials science. Adhesion applications are supported by ionogel properties, especially crosslinking and solvation tunable interactions with adjacent phases. Antimicrobial and antifouling applications are consequences of the cationic nature of PILs. Similarly, emulsion and dispersion applications rely on tunable solvation of functional groups and on how such groups interact with continuous phases and substrates. Catalysis is another significant application, and this is an historical tie between ILs and PILs. This component also provides a connection to diverse and porous carbon phases templated by PILs that are catalysts or serve as supports for catalysts. Devices, including sensors and actuators, also rely on solvation tuning and stimuliresponsiveness that include photo and electrochemical stimuli. We conclude our view of applications with 3D printi...

show abstract

Section: Graftingmentioning

confidence: 99%

mentioning

confidence: 99%