The TbNiIn1-xMx (M = Al, Ge, Sb) systems

Horiacha, Myroslava; Halyatovskii, B.; Horiacha, S.; Nychyporuk, G.; Pöttgen, Rainer; Zaremba, Vasyl’ I.

doi:10.30970/vch.6101.052

Cited by 4 publications

(2 citation statements)

References 22 publications

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“…The refined parameter c of unite cell a bit increases with increasing aluminum content, while parameter a and cell volume V decrease. Such behavior of variation of the parameters for the solid solution was already observed in the similar systems RNiIn1-xAlx with ZrNiAl-type structure [14][15][16]. The refinement of crystal structure from powder diffraction data for the HoNiIn0.6Al0.4 sample confirms substituting indium by aluminum atoms in the crystallographic site 3g (ZrNiAl type structure, space group P-62m) (Fig.…”

Section: Resultssupporting

confidence: 76%

Crystal structure and electrochemical hydrogenation of HoNiIn1-xAlx (x = 0-1) solid solution

Nychyporuk,

Kordan,

Horiacha

et al. 2023

Phys. Chem. Solid St.

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The influence of the substitution of indium by aluminum in HoNiIn compound at 873 K was investigated in the full concentration range by means of powder X-ray diffraction and EDX analysis. The formation of continuous solid solution was determined and changes of the unit cell parameters were calculated: HoNiIn1.0–0Al0–1.0 (ZrNiAl-type structure, space group P-62m, a = 0.74343(4)–0.69959(6) nm and c = 0.37472(3)–0.38289(4) nm, V = 0.17936(2)–0.16229(3) mn3). The best discharge capacity after electrochemical hydrogenation studies of HoNiIn1-xAlx solid solution is observed for battery prototypes with HoNiIn0.2Al0.8- and HoNiIn0.4Al0.6-based electrodes.

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Section: Resultssupporting

confidence: 76%

Crystal structure and electrochemical hydrogenation of HoNiIn1-xAlx (x = 0-1) solid solution

Nychyporuk,

Kordan,

Horiacha

et al. 2023

Phys. Chem. Solid St.

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“…6). Порівняння досліджених систем з вивченими раніше системами RNiIn 1-x M x (R = La, Ce, Y, Gd, Tb; M = Al, Ga, Ge, Sb) [19,20,[32][33][34][35][36][37] свідчить про спільні тенденції у характері взаємодії компонентів у них: між ізоструктурними сполуками еквіатомного складу простежується утворення неперервних рядів твердих розчинів, якщо ж сполуки мають різну структуру -формуються обмежені тверді розчини заміщення різної протяжності зі структурами вихідних сполук або утворюються нові фази, як у системі LaNiIn 1-x Ga x [38].…”

Section: а б вunclassified

THE RCuIn1–xGax (R = La, Ce) SYSTEMS AT 870 K

Zaremba¹,

Nychyporuk²,

Horiacha³

et al. 2021

Proc. Shevchenko Sci. Soc. Chem. Sci.

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The solid solutions TbCuIn_1–x M _x (M = Al, Ga)

Horiacha

Nychyporuk

Pöttgen

et al. 2022

Zeitschrift Für Naturforschung B

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The complete solid solutions TbCuIn1–x M x (M = Al, Ga) were studied by powder X-ray diffraction and scanning electron microscopy for samples equilibrated at T = 873 K. The influence of In substitution by Al or Ga, the solubility ranges and the changes of unit cell parameters have been determined: TbCuIn1.0–0Al0–1.0 (ZrNiAl type, space group P 6 ‾ 2 $\overline{6}2$ m, a = 0.7457(1)–0.7035(1), c = 0.3958(1)–0.4044(1) nm, V = 0.1906–0.1733 nm3); TbCuIn1–0.8Ga0–0.2 (ZrNiAl type, a = 0.74569(5)–0.73882(13), с = 0.39582(3)–0.39663(14) nm, V = 0.1906–0.1875 nm3); TbCuIn0.3–0Ga0.7–1.0 (KHg2 type, Imma, а = 0.43943(9)–0.43750(5), b = 0.70833(12)–0.70537(6), с = 0.74866(12)–0.74525(7) nm, V = 0.2330–0.2300 nm3). The crystal structure of TbCuIn0.42(1)Al0.58(1) was refined from single-crystal X-ray diffractometer data: ZrNiAl type, P 6 ‾ 2 $\overline{6}2$ m, a = 0.71633(6), c = 0.40785(3) nm, wR2 = 0.0379, 291 F 2 values and 16 variables. The basic crystal chemical features are discussed.

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The TbNiIn1-xMx (M = Al, Ge, Sb) systems

Cited by 4 publications

References 22 publications

Crystal structure and electrochemical hydrogenation of HoNiIn1-xAlx (x = 0-1) solid solution

Crystal structure and electrochemical hydrogenation of HoNiIn1-xAlx (x = 0-1) solid solution

THE RCuIn1–xGax (R = La, Ce) SYSTEMS AT 870 K

The solid solutions TbCuIn_1–x M _x (M = Al, Ga)

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The TbNiIn1-xMx (M = Al, Ge, Sb) systems

Cited by 4 publications

References 22 publications

Crystal structure and electrochemical hydrogenation of HoNiIn1-xAlx (x = 0-1) solid solution

Crystal structure and electrochemical hydrogenation of HoNiIn1-xAlx (x = 0-1) solid solution

THE RCuIn1–xGax (R = La, Ce) SYSTEMS AT 870 K

The solid solutions TbCuIn1–x M x (M = Al, Ga)

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The solid solutions TbCuIn_1–x M _x (M = Al, Ga)