1979
DOI: 10.1016/0009-2614(79)85162-3
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The temperature dependence of collision-induced state changes

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Cited by 22 publications
(1 citation statement)
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“…H, C1, and F quench CO 2 rapidly compared to noble gases, such as He, Ne, and Xe (Chu etal., 1983;Flynn and Weston, 1986). The large cross sections and the negative temperature dependences at low collision energies for such systems have been ascribed to the formation of long-lived collision complexes in the presence of strong attractive chemical, hydrogen bonding or Van der Waals forces (Ewing, 1978;Linet al, 1979;Parmenter and Seaver, 1979;Gordon, 1981 ;McClelland et al, 1979). The lifetime of a collision complex is longer at low collision energies, and the longer-lived the collision complex, the greater the probability that the energy in the vibrational mode may flow into the weak bond of the complex and cause its dissociation.…”
Section: Ir Heating and 15-pm Coolingmentioning
confidence: 99%
“…H, C1, and F quench CO 2 rapidly compared to noble gases, such as He, Ne, and Xe (Chu etal., 1983;Flynn and Weston, 1986). The large cross sections and the negative temperature dependences at low collision energies for such systems have been ascribed to the formation of long-lived collision complexes in the presence of strong attractive chemical, hydrogen bonding or Van der Waals forces (Ewing, 1978;Linet al, 1979;Parmenter and Seaver, 1979;Gordon, 1981 ;McClelland et al, 1979). The lifetime of a collision complex is longer at low collision energies, and the longer-lived the collision complex, the greater the probability that the energy in the vibrational mode may flow into the weak bond of the complex and cause its dissociation.…”
Section: Ir Heating and 15-pm Coolingmentioning
confidence: 99%