1984
DOI: 10.1088/0026-1394/20/3/002
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The Temperature Dependence of the Diamagnetic Shielding Correction for Proton NMR in Water

Abstract: The fractional frequency shift in the nmr signal from protons in a spherically-shaped pure water sample has been measured directly as -10.36(30) X OC-l over the range 5°C to 45 "C. A revised value of 25.69(14) x is suggested for the proton diamagnetic shielding correction in water at 25 "C, leading to pb(2.5 OC)/pB = 0.001 520 993 136(17).

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Cited by 36 publications
(9 citation statements)
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“…The ratio of the electron to proton g factors in hydrogen is known to 9 ppb [34], and the bound-state corrections relating the g factor of a free proton to one in hydrogen were calculated in [35,36]. We also corrected for the measured temperature dependence of the shielding constant, dσ(H 2 O, T )/dT = 10.36(30) × 10 −9 /K [37].…”
Section: Absolute Calibration Probementioning
confidence: 99%
“…The ratio of the electron to proton g factors in hydrogen is known to 9 ppb [34], and the bound-state corrections relating the g factor of a free proton to one in hydrogen were calculated in [35,36]. We also corrected for the measured temperature dependence of the shielding constant, dσ(H 2 O, T )/dT = 10.36(30) × 10 −9 /K [37].…”
Section: Absolute Calibration Probementioning
confidence: 99%
“…where δ T corrects for the temperature dependence of the diamagnetic shielding of H 2 O between the temperature T of the measurement and the chosen reference temperature T r = 34.7 °C [38,51,52]; δ b is a correction dependent on water magnetic susceptibility and sample shape; and δ t is the sum of corrections for the probe materials and other effects related to the probe. The probe temperature T , typically close to 26 °C, was measured to 0.5 °C 2 In principle, the corrections would be multiplicative but we use the approximation with a PT-1000 sensor installed in the probe near the sample.…”
Section: A Systematic Effectsmentioning
confidence: 99%
“…The bound-state correction relating the g-factor of the proton bound in hydrogen to the free proton are calculated in References [68,69]. The temperature dependence of σ is corrected for using dσ(H 2 O, T )/dT = 10.36(30) × 10 −9 / • C [70]. The free proton frequency is determined to an accuracy of 0.05 ppm.…”
Section: Calibration Of the Trolley Probesmentioning
confidence: 99%