Metallic iron (Fe 0 ) or zero-valent iron (ZVI) has been extensively used for water remediation during the past three decades. It has been proven to be effective in treating waters polluted with chlorinated aliphatics, dyes, heavy metals, pathogens, radionuclides and more. Fe 0 is an abundant, low-cost, and non-toxic reactive metal. Its environmental reactivity is justified by the negative electrode potential of the redox couple Fe II /Fe 0 (E 0 = -0.44 V). These characteristics of Fe 0 have been exploited in a wide range of remediation technologies, including both permeable reactive barriers (PRBs) for in-situ groundwater remediation, and filtration systems (Fe 0 filters) for decentralized water treatment. Fe 0 PRBs and Fe 0 water filters employ Fe 0 and other solid aggregates (e.g. MnO2, pyrite, sand) to passively remediate polluted waters in a reactive zone. A polluted water flowing through a reactive zone packed with Fe 0 is ideally satisfactorily decontaminated, meaning that the contaminant concentrations in the outflow are below regulatory levels (called maximum contamination level -MCL).