The Theory of Coherent Synchronized Reactions: Chemical Interference Logics

Abstract

Various types of possible interactions between reactions are discussed. Some of them are united by the general idea of chemical reaction interference. The ideas on conjugated reactions are broadened and the determinant formula is deduced; the coherence condition for chemical interference is formulated and associated phase shifts are determined. It is shown how interaction between reactions may be qualitatively and quantitatively assessed and kinetic analysis of complex reactions with under researched mechanisms may be performed with simultaneous consideration of the stationary concentration method. Using particular examples, interference of hydrogen peroxide dissociation and oxidation of substrates is considered. Therefore macrokinetic theory of coherent synchronized reactions is offered.

Kinetics and Mechanism of the Reaction of Coherently Synchronized Oxidation and Dehydrogenation of Cyclohexane by Hydrogen Peroxide

“…Biomimetic catalyst [11], which simulates the basic functions of the enzyme group of oxidoreductase -catalase and monooxygenase, was used as the catalyst here. Characterised by its highly active and selective action these biomimetic catalysts are synthesized based on iron-porphyrin complexes 01002-p. 2 …”

“…Inducing effect of hydrogen peroxide on synchronous oxidation reaction is accompanied by the occurrence of two interconnected and interacting reactions [1,2]. The reaction of Н 2 О 2 decomposition (primary) generates the leading active OH HO free radicals in a system.…”

The Theory of Conjugate Reactions in the Context of Modern Ideas

“…This contributed to the creative development of the theory of conjugate processes. Thus a series of papers [1]- [6] was devoted to the development of this "half-forgotten branch of chemical kinetics of the past", where "according to N.A. Shilov the concept of interference of chemical reactions is a natural generalization and nontrivial development of the idea of conjugate oxidation reactions" (from the foreword to the monograph by O.M Poltorak [1]).…”

“…-in contrast to parallel, sequential and parallel-sequential reactions, an induced (secondary) reaction cannot be carried out separately from the primary reaction; -the spontaneous target reaction can also be modified under influence of induction and under certain conditions proceed with a high rate; -the reaction system, in which chemical induction is realized, contains two or more components. The concept of chemical interference is put forward by us, as a phenomenon consisting in the fact that reactions occurring synchronously in a chemical system, can mutually strengthen and weaken, and in this state they are necessarily coherent [1]- [6].…”

Kinetics and Mechanism of the Reaction of Coherently Synchronized Oxidation and Dehydrogenation of Cyclohexane by Hydrogen Peroxide

“…Inducing effect of hydrogen peroxide on synchronous oxidation reaction is accompanied by the occurrence of two interconnected and interacting reactions [1,2]. The reaction of Н 2 О 2 decomposition (primary) generates the leading active OH  and  2 HO free radicals in a system.…”