The thermal decomposition of cu(II) complex of 3,5‐dinitrosalicylic acid

Heda, B. D.; Khadikar, Padmakar V.

doi:10.1002/bscb.19800890502

Bulletin des Soc Chimique

1980

DOI: 10.1002/bscb.19800890502

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The thermal decomposition of cu(II) complex of 3,5‐dinitrosalicylic acid

B. D. Heda

Padmakar V. Khadikar

Abstract: COMPLEX O F 3,5-DINITROSALICYLIC A C I D B . D . H e d a a n d P . V . K h a d i k a r D e p a r t m e n t o f C h e m i s t r y , U n i v e r s i t y o f I n d o r e , V i g y a n B h a w a n , Khandwa R o a d , I n d o r e -4 5 2 0 0 1 , I N D I A .

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1985

1988

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Cited by 6 publications

References 12 publications

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Structure and thermal characterization of tris-thallium(III) glycollate

Khadikar

1987

Journal of Thermal Analysis

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The thermal decarboxylation of TI(GLA)3 (where GLA stands for the anion ofglycollic acid) was studied by TG, DTG and DTA techniques. The results showed the escape of all three glycollic acid moieties in a single step. The I R spectra of the ligand and the complex indicated the bidentate character of carboxylate ion and the fact that the proton from the hydroxy group is not replaced during complex formation, The various kinetic and thermodynamic parameters were estimated from analysis of the TG, DTG and DTA curves of the sample, employing several computational methods. Precise results were then obtained by the method of least squares and are discussed.The thermal decomposition of metal carboxylates has attracted great interest during recent years [1,2]. However, work on the thermal decomposition of heavy metal carboxylates started only a short time ago [3]. Recently, we reported on the thermal dehydration and decomposition of metal complexes of salicylic and nuclear substituted salicylic acids [4][5][6][7][8][9]. The work on the thermal decomposition of metal complexes of hydroxy acids is very limited. As an extension of our previous studies [4][5][6][7][8][9], the present report deals with the thermal decarboxylation of TI(III) glycollate, with a view to understanding the mechanism of the decomposition and the nature of the decomposition products. The characterization ofTl(IlI) glycollate was carried out through elemental analysis, IR spectra, TG, DTG and DTA studies. Attempts were also made to estimate the kinetic parameters from thermal studies, employing different computational methods, e.g. the Horowitz-Metzger

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Structure and thermal characterization of tris-thallium(III) glycollate

Khadikar

1987

Journal of Thermal Analysis

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IR, TG, DTG and DTA studies of bis-(4-aminosalicylato)-diaquo complexes of VO(II), Cu(II), Ni(II), Co(II), Fe(II) and Mn(II)

Khadikar¹,

Ali²,

Farooqui³

et al. 1985

Thermochimica Acta

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Preparation, structure and thermal decomposition of some metal complexes of 5-nitrosalicylhydrazide (5NSH)

1986

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The thermal decomposition of cu(II) complex of 3,5‐dinitrosalicylic acid

Abstract: COMPLEX O F 3,5-DINITROSALICYLIC A C I D B . D . H e d a a n d P . V . K h a d i k a r D e p a r t m e n t o f C h e m i s t r y , U n i v e r s i t y o f I n d o r e , V i g y a n B h a w a n , Khandwa R o a d , I n d o r e -4 5 2 0 0 1 , I N D I A .

Cited by 6 publications

References 12 publications

Structure and thermal characterization of tris-thallium(III) glycollate

Structure and thermal characterization of tris-thallium(III) glycollate

IR, TG, DTG and DTA studies of bis-(4-aminosalicylato)-diaquo complexes of VO(II), Cu(II), Ni(II), Co(II), Fe(II) and Mn(II)

Preparation, structure and thermal decomposition of some metal complexes of 5-nitrosalicylhydrazide (5NSH)

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